Ferroelastic lattice instability during the thermally enhanced reaction of MSE

A p-dimethylaminobenzenesulfonate (MSE) polycrystalline powder is converted to the zwitterionic product p-trimethylammoniumbenzenesulfonate (ZWT) by a chemical thermally induced reaction at T= 55,5°C. Experimental results obtained by differential scanning calorimetry and 13C solid-state NMR indicate...

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Published in:Ferroelectrics 1999-09, Vol.233 (1), p.129-137
Main Authors: Even, J., Bertault, M., Gallier, J., Rouede, D.
Format: Article
Language:English
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Ferroelastic
MSE
structural phase transition
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creator Even, J.
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Rouede, D.
description A p-dimethylaminobenzenesulfonate (MSE) polycrystalline powder is converted to the zwitterionic product p-trimethylammoniumbenzenesulfonate (ZWT) by a chemical thermally induced reaction at T= 55,5°C. Experimental results obtained by differential scanning calorimetry and 13C solid-state NMR indicate that reaction-induced stress gives rise to a ferroelastic lattice instability during the thermally enhanced solid state reaction of methyl p-dimethylaminobenzenesulfonate (MSE).
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subjects Ferroelastic
MSE
structural phase transition
title Ferroelastic lattice instability during the thermally enhanced reaction of MSE
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