2,6-Dicarboxypyridinium Fluorochromate-Promoted Oxidation of Alkyl-Arenes into Carbonyl Compounds Under Nonaqueous and Aprotic Conditions

Benzylic C-H oxidation of a wide variety of alkyl- and cycloalkyl arenes employing 2,6-dicarboxypyridinium fluorochromate under mild reaction conditions is described. The corresponding carbonyl compounds are obtained in good to excellent yields.

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Bibliographic Details
Published in:Synthetic communications 2012-03, Vol.42 (5), p.678-685
Main Authors: Sarrafi, Yaghoub, Tajbakhsh, Mahmood, Hosseinzadeh, Rahman, Sadatshahabi, Marzieh, Alimohammadi, Kamal
Format: Article
Language:English
Subjects:
2,6-dicarboxypyridinium fluorochromate
Alkyl-arenes
Carbon
carbonyl compounds
Chemical reactions
Oxidation
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Description
Summary:Benzylic C-H oxidation of a wide variety of alkyl- and cycloalkyl arenes employing 2,6-dicarboxypyridinium fluorochromate under mild reaction conditions is described. The corresponding carbonyl compounds are obtained in good to excellent yields.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397911.2010.529228