Barbier-Type Allylation of Aldehydes with Active Metallic Antimony

Highly reactive antimony, prepared by the NaBH 4 reduction of SbCl 3 , induced allylation of aldehydes with allylic bromide in DMF/H 2 O solvent to give good yields of the corresponding homoallylic alcohols with high regio- and chemo- selectivity.

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Bibliographic Details
Published in:Synthetic communications 1997-08, Vol.27 (16), p.2761-2767
Main Authors: Ren, Ping-Da, Jin, Qi-Hui, Yao, Zi-Peng
Format: Article
Language:English
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Description
Summary:Highly reactive antimony, prepared by the NaBH 4 reduction of SbCl 3 , induced allylation of aldehydes with allylic bromide in DMF/H 2 O solvent to give good yields of the corresponding homoallylic alcohols with high regio- and chemo- selectivity.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397919708004149