Polymeric Coordination Compounds Derived from Transition Metal (II) with Bis-dentate Ligand: Synthesis, Spectroscopic, Magnetic and Thermal Studies

Polymeric compounds have been synthesized using the ligand [(5,5′-(3,3′-((4-Hydroxyphenyl)methylene)bis(1H-indole-3,1-diyl)bis(methylene)diquinolin-8-ol)] (HMBIQ) with Mn(II), Co(II), Ni(II), Cu(II), and Zn(II). The ligand has been characterized by 1 H and 13 C-NMR spectroscopy. The coordination pol...

Full description

Saved in:
Bibliographic Details
Published in:International journal of polymeric materials 2012-04, Vol.61 (4), p.276-287
Main Authors: Patel, Darshana J., Patel, Hasmukh S.
Format: Article
Language:English
Subjects:
Acetone
Chemical compounds
Coordination compounds
coordination polymers
Electronics
Ethyl alcohol
Ligands
Methyl alcohol
Molecules
NMR
Nuclear magnetic resonance
Solvents
spectroscopic
Spectroscopy
thermal and magnetic studies
Thermogravimetric analysis
transition metal ions
Transition metals
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Polymeric compounds have been synthesized using the ligand [(5,5′-(3,3′-((4-Hydroxyphenyl)methylene)bis(1H-indole-3,1-diyl)bis(methylene)diquinolin-8-ol)] (HMBIQ) with Mn(II), Co(II), Ni(II), Cu(II), and Zn(II). The ligand has been characterized by 1 H and 13 C-NMR spectroscopy. The coordination polymers have been characterized by elemental analyses, magnetic measurements, thermogravimetric analyses, electronic and infrared spectra. The coordination compounds are colored and the central metal ions are octahedrally coordinated with two water molecules and the ligand. The polymers are insoluble in all common organic solvents such as acetone, methanol, ethanol, DMF, and DMSO.
ISSN:0091-4037
1563-535X
DOI:10.1080/00914037.2011.584222