Synthesis and Investigation of Properties of the Optically Transparent Carbochain Copolymers with Elementorganical and Hydroxy Groups in the Side Chain of Macromolecules

The carbochain co-polymers with elementorganical and hydroxy groups in the side chain of macromolecules have been synthesized. The reactions of the radical co-polymerization of perfluoroalkyl(meth)acrylates and siliconorganic methacrylates with dimethylvinylacetylenylcarbinol in mass were studied. B...

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Bibliographic Details
Published in:International journal of polymeric materials 1998-02, Vol.39 (3-4), p.237-253
Main Authors: Lekishvili, N., Asatiani, L., Andguladze, N., Lekishvili, G., Guliashvili, T.
Format: Article
Language:English
Subjects:
Fluoromethacrylates
light conduction
optical adhesives
organosilicon methacrylates
reactivity
vinylacetylenylcarbinol
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Summary:The carbochain co-polymers with elementorganical and hydroxy groups in the side chain of macromolecules have been synthesized. The reactions of the radical co-polymerization of perfluoroalkyl(meth)acrylates and siliconorganic methacrylates with dimethylvinylacetylenylcarbinol in mass were studied. By using NMR- 1 H spectroscopy of high resolution, UV, IR spectroscopy and GLC methods the structure and the composition of co-polymers, constants of copolymerization r ij r ji , the distribution of homo and heterodiads in macromolecular chain of the co-polymers were determined. The optical, thermomechanical properties and the thermooxidative stability of the co-polymers were researched. The possibility of their application for production of the optical adhesives was determined.
ISSN:0091-4037
1563-535X
DOI:10.1080/00914039808039771