Synthesis and Vibrational Spectra of Metal Halide Complexes of 3,5-Lutidine in Relation to their Structures

The synthesis and the results of an infrared and Raman spectroscopic study are reported for metal(II) halide 3,5-lutidine (3,5-dimethylpyridine) complexes, M(3,5L) 2 X 2 , M = Cd or Zn, X = Cl, Br or I; M = Co, Cu or Hg, X = Cl or Br; M = Mn, Fe or Ni, X = Cl, 3,5L = 3,5-lutidine. Vibrational assign...

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Bibliographic Details
Published in:Synthesis and reactivity in inorganic and metal-organic chemistry 1997-09, Vol.27 (8), p.1235-1248
Main Authors: Yurdakul, Şenay, Akyüz, Sevim, Davies, J. Eric D.
Format: Article
Language:English
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Summary:The synthesis and the results of an infrared and Raman spectroscopic study are reported for metal(II) halide 3,5-lutidine (3,5-dimethylpyridine) complexes, M(3,5L) 2 X 2 , M = Cd or Zn, X = Cl, Br or I; M = Co, Cu or Hg, X = Cl or Br; M = Mn, Fe or Ni, X = Cl, 3,5L = 3,5-lutidine. Vibrational assignments are given for all the observed bands. Some structure-spectra correlations were found. For a given series of isomorphous complexes the sum of the difference of the values of the vibrational modes of 3,5-lutidine between the free ligand as liquid and the complexed ligand was found to increase in the order of the second ionization potentials of the metals. The frequency shifts were also found to depend on the halogen. Referee I: A. Oki Referee II: W. T. Tikkanen
ISSN:0094-5714
1532-2440
DOI:10.1080/00945719708000260