COPPER(III) COORDINATION COMPOUNDS: CLASSIFICATION AND ANALYSIS OF CRYSTALLOGRAPHIC AND STRUCTURAL DATA

Copper is classed as a transition metal both from its physico-chemical properties and its biochemical behavior. This review includes thirty formally copper(III) compounds where crystal structure has been determined. Coordination number four dominates with mostly a square-planar arrangement about the...

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Bibliographic Details
Published in:Journal of coordination chemistry 2000-06, Vol.50 (1), p.323-338
Main Authors: Melník, Milan, Kabešová, Mária
Format: Article
Language:English
Subjects:
coordination complexes
Copper(III)
review
stxructures
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Summary:Copper is classed as a transition metal both from its physico-chemical properties and its biochemical behavior. This review includes thirty formally copper(III) compounds where crystal structure has been determined. Coordination number four dominates with mostly a square-planar arrangement about the copper(III) atom. Sulfur donor ligands by far prevail. In general the Cu-L bond distance elongated with a decreased oxidation state of copper in the sequence: Cu(III)-L > Cu(II)-L > Cu(I)-L. Examples of distortion isomerism exist.
ISSN:0095-8972
1029-0389
DOI:10.1080/00958970008054938