The synthesis and characterization of new phthalocyanines containing hexaazadithia macrobicyclic moieties

The new metal-free and metallo phthalocyanines (4) and (5) bearing four tetrasubstituted hexaazadithia macrobicycles on peripheral positions, have been synthesized. Phthalonitrile (3) has been synthesized from the reaction of (1,3,6,9,11,14 hexaazatricyclo [12.2.1.1 6,9 ]) (1) and 1,2-bis(2-iodomerc...

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Bibliographic Details
Published in:Journal of coordination chemistry 2006-11, Vol.59 (17), p.1929-1935
Main Authors: Kantekİn, Halİt, KiliÇaslan, Meltem B., Şahinbaş, H. Zeki, Gök, Yaşar
Format: Article
Language:English
Subjects:
Cryptand
Macrobicyclic
Metallophthalocyanine
Phthalocyanine
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Summary:The new metal-free and metallo phthalocyanines (4) and (5) bearing four tetrasubstituted hexaazadithia macrobicycles on peripheral positions, have been synthesized. Phthalonitrile (3) has been synthesized from the reaction of (1,3,6,9,11,14 hexaazatricyclo [12.2.1.1 6,9 ]) (1) and 1,2-bis(2-iodomercaptoethyl)-4,5-dicyanobenzene (2). The new compounds were characterized by elemental analysis, and IR, 1 H, 13 C-NMR, UV-Visible and mass spectral data.
ISSN:0095-8972
1029-0389
DOI:10.1080/00958970600667063