Synthesis, structural investigations and biological studies on symmetrically substituted 4,4′,4″,4″′- tetra-methoxyphenylimino phthalocyanine complexes

The synthesis and characterization of novel metal(II) 4,4′,4″,4″′-tetra-methoxyphenylimino substituted phthalocyanines (MImPc) of copper(II), cobalt(II), nickel(II) and zinc(II) by condensing the 4,4′,4″,4″′-tetra amino phthalocyanines with anisaldehyde are described. The dark bluish green colored t...

Full description

Saved in:
Bibliographic Details
Published in:Journal of coordination chemistry 2007-06, Vol.60 (12), p.1255-1267
Main Authors: Moinuddin Khan, M. H., Fasiulla, Harish, M. N. K., Keshavayya, J., Venugopala Reddy, K. R.
Format: Article
Language:English
Subjects:
Crystallinity
Elemental
Magnetic susceptibility
Tetramethoxyphenylimino phthalocyanines
Thermal
Variations
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The synthesis and characterization of novel metal(II) 4,4′,4″,4″′-tetra-methoxyphenylimino substituted phthalocyanines (MImPc) of copper(II), cobalt(II), nickel(II) and zinc(II) by condensing the 4,4′,4″,4″′-tetra amino phthalocyanines with anisaldehyde are described. The dark bluish green colored tetraimino substituted phthalocyanine derivatives are characterized by various physico-chemical techniques, elemental analysis, magnetic susceptibility, electronic, and IR spectra, powder X-ray diffraction and thermo gravimetric analysis (TGA) to check the structural integrity and purity. The variations of magnetic moment as a function of field strength indicated the presence of intermolecular co-operative interactions. The complexes are also evaluated for their antifungal and antibacterial activities.
ISSN:0095-8972
1029-0389
DOI:10.1080/00958970601099811