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Platinum(IV) and palladium(II) thiosemicarbazide and thiodiamine complexes: A spectral and antibacterial study
Platinum(IV) and palladium(II) complexes [Pt(L) 2 Cl 2 ] and [Pd(L)Cl 2 ], [where, L = 1,1-diphenyl-2-thiosemicarbazide (L 1 ) and (1,1-diphenyl-2-thio)-1,3-propanediamine (L 2 ) have been synthesized. The thiosemicarbazides and thiodiamines exist as the thione-thiol tautomer and coordinate as a bid...
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Published in: | Journal of coordination chemistry 2007-09, Vol.60 (18), p.1923-1932 |
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Main Authors: | , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Platinum(IV) and palladium(II) complexes [Pt(L)
2
Cl
2
] and [Pd(L)Cl
2
], [where, L = 1,1-diphenyl-2-thiosemicarbazide (L
1
) and (1,1-diphenyl-2-thio)-1,3-propanediamine (L
2
) have been synthesized. The thiosemicarbazides and thiodiamines exist as the thione-thiol tautomer and coordinate as a bidentate N-S ligand. The ligands are monobasic bidentate. The complexes have been characterized by elemental analysis, IR, mass, electronic and 1H NMR spectroscopic studies. In vitro antibacterial studies have also been carried out for some complexes. |
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ISSN: | 0095-8972 1029-0389 |
DOI: | 10.1080/00958970601183128 |