Molecular design of mononuclear complexes of acyclic Schiff-base ligands

Data on molecular design of various types of mononuclear complexes of Schiff bases are generalized. Factors for variation of fine structure of Schiff-base ligand systems (metallocycle sizes and their number, nature of donor centers, aldehyde and amine fragments, co-ligands) are examined. A systemati...

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Bibliographic Details
Published in:Journal of coordination chemistry 2009-01, Vol.62 (2), p.151-204
Main Authors: Garnovskii, A. D., Vasilchenko, I. S., Garnovskii, D. A., Kharisov, B. I.
Format: Article
Language:English
Subjects:
C-, N-, O-, S-, Se-, Te- Salen chelates
Di- and oligodentate azomethine ligands with N.C-, N.N-, N.P-, N.O-, N.S-, N.Se-, N.Te-donor centers
Mononuclear complexes
Schiff bases
Standard and nonstandard structures
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Summary:Data on molecular design of various types of mononuclear complexes of Schiff bases are generalized. Factors for variation of fine structure of Schiff-base ligand systems (metallocycle sizes and their number, nature of donor centers, aldehyde and amine fragments, co-ligands) are examined. A systematization of Salen complexes is offered. Electronic configurations of p- and d-metals in the coordination and organometallic compounds are taken into account in a series of chelate structures. Non-standard structures are emphasized, including various ligand chelates and molecular complexes.
ISSN:0095-8972
1029-0389
DOI:10.1080/00958970802398178