PHYSICAL PROPERTIES AND STRUCTURES OF PSEUDOHALOGENOCOPPER (II) COMPLEXES WITH PHENANTHROLINE

Electronic, IR and EPR spectra of eight Cu(II) complexes with trigonal-bipyramidal, tetragonal-bipyramidal and tetragonal-pyramidal coordination polyhedra containing phenanthroline and pseudohalogenide ligands were examined and their interrelationships with molecular and crystal structures evaluated...

Full description

Saved in:
Bibliographic Details
Published in:Journal of coordination chemistry 1998-01, Vol.43 (1), p.41-51
Main Authors: Maŝlejová, Anna, Potoĉṋák, Ivan, Ŝima, Jozef, Kabeŝová, Mária
Format: Article
Language:English
Subjects:
copper(II)
phenanthroline
pseudohalide
spectroscopy
structure
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Electronic, IR and EPR spectra of eight Cu(II) complexes with trigonal-bipyramidal, tetragonal-bipyramidal and tetragonal-pyramidal coordination polyhedra containing phenanthroline and pseudohalogenide ligands were examined and their interrelationships with molecular and crystal structures evaluated. Along with the usual trigonal-bipyramidal environment of Cu(II), tetragonal symmetry for four complexes was observed. The origin of this tetragonal symmetry is connected with intermolecular interaction of phenanthroline with pseudohalide ligands.
ISSN:0095-8972
1029-0389
DOI:10.1080/00958979808022869