Loading…
Synthesis and x-ray crystal structure of a 24-membered macrocyclic binuclear cadmium(ii) complex with pendant arms
A new binuclear cadmium(II) macrocyclic complex has been synthesized by [2 + 2] Schiff base condensation of tris(2-aminoethyl)amine (tren) with sodium 2, 6-diformyl-4-bromo-phenolate (sdbp) in the presence of Cd 2+ ion. The crystal structure of the complex [Cd 2 L](ClO 4 ) 2 0.5CH 3 OH has been dete...
Saved in:
| Published in: | Journal of coordination chemistry 1998-04, Vol.43 (4), p.281-288 |
|---|---|
| Main Authors: | , , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c344t-a0fe6bc7832eac04ffdf7c244f4388c1731c92a66f6a7a0f5e6969e8f76682953 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c344t-a0fe6bc7832eac04ffdf7c244f4388c1731c92a66f6a7a0f5e6969e8f76682953 |
| container_end_page | 288 |
| container_issue | 4 |
| container_start_page | 281 |
| container_title | Journal of coordination chemistry |
| container_volume | 43 |
| creator | Xu, Xin-You Wang, Zhi-Lin Luo, Qin-Hui Shen, Meng-Chang Zhou, Xiang-Ge Zhou, Zhong-Yuan |
| description | A new binuclear cadmium(II) macrocyclic complex has been synthesized by [2 + 2] Schiff base condensation of tris(2-aminoethyl)amine (tren) with sodium 2, 6-diformyl-4-bromo-phenolate (sdbp) in the presence of Cd
2+
ion. The crystal structure of the complex [Cd
2
L](ClO
4
)
2
0.5CH
3
OH has been determined by X-ray methods. Crystals are mono-clinic, space group P2
1
/c with a = 11.633(15), b = 16.370(2), c = 21.193(2) Å, β = 96.121(12)°, Z= 4, V= 4013.0(8) Å
3
, F(000) = 2180, Dc., = 1.841 g cm
−3
, μ = 32.46 cm
−1
, R = 0.049, R
w
= 0.069. Two cadmium(II) ions are bridged by two μ
2
-phenoxy oxygen atoms. Each cadmium lies in a N
4
O
2
coordination environment. Coordination geometry around Cd(II) is a capped trigonal bipyramid. Coordination of phenoxy oxygens and terminal amino groups enhances the stability of the complex. |
| doi_str_mv | 10.1080/00958979808230441 |
| format | article |
| fullrecord | <record><control><sourceid>crossref_infor</sourceid><recordid>TN_cdi_crossref_primary_10_1080_00958979808230441</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1080_00958979808230441</sourcerecordid><originalsourceid>FETCH-LOGICAL-c344t-a0fe6bc7832eac04ffdf7c244f4388c1731c92a66f6a7a0f5e6969e8f76682953</originalsourceid><addsrcrecordid>eNqFkEtLAzEUhYMoWKs_wF2WuhjNq3mAGym-oOBCXQ-3mYRGJjMlSWnn3zul7oq4uotzvnMuB6FrSu4o0eSeEDPTRhlNNONECHqCJpQwUxGuzSma7PVqNLBzdJHzNyGUc6YmKH0MXVm5HDKGrsG7KsGAbRpygRbnkja2bJLDvceAmaiii0uXXIMj2NTbwbbB4mXoNrZ1kLCFJoZNvAnhFts-rlu3w9tQVnjtuga6giHFfInOPLTZXf3eKfp6fvqcv1aL95e3-eOislyIUgHxTi6t0pw5sER433hlmRBecK0tVZxaw0BKL0GN5pmTRhqnvZJSMzPjU0QPueOnOSfn63UKEdJQU1LvR6uPRhsZdWBC5_sUYduntqkLDG2ffILOhnxM1WVXRvLhX5L_XfwDkXyGUQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Synthesis and x-ray crystal structure of a 24-membered macrocyclic binuclear cadmium(ii) complex with pendant arms</title><source>Taylor and Francis Science and Technology Collection</source><creator>Xu, Xin-You ; Wang, Zhi-Lin ; Luo, Qin-Hui ; Shen, Meng-Chang ; Zhou, Xiang-Ge ; Zhou, Zhong-Yuan</creator><creatorcontrib>Xu, Xin-You ; Wang, Zhi-Lin ; Luo, Qin-Hui ; Shen, Meng-Chang ; Zhou, Xiang-Ge ; Zhou, Zhong-Yuan</creatorcontrib><description>A new binuclear cadmium(II) macrocyclic complex has been synthesized by [2 + 2] Schiff base condensation of tris(2-aminoethyl)amine (tren) with sodium 2, 6-diformyl-4-bromo-phenolate (sdbp) in the presence of Cd
2+
ion. The crystal structure of the complex [Cd
2
L](ClO
4
)
2
0.5CH
3
OH has been determined by X-ray methods. Crystals are mono-clinic, space group P2
1
/c with a = 11.633(15), b = 16.370(2), c = 21.193(2) Å, β = 96.121(12)°, Z= 4, V= 4013.0(8) Å
3
, F(000) = 2180, Dc., = 1.841 g cm
−3
, μ = 32.46 cm
−1
, R = 0.049, R
w
= 0.069. Two cadmium(II) ions are bridged by two μ
2
-phenoxy oxygen atoms. Each cadmium lies in a N
4
O
2
coordination environment. Coordination geometry around Cd(II) is a capped trigonal bipyramid. Coordination of phenoxy oxygens and terminal amino groups enhances the stability of the complex.</description><identifier>ISSN: 0095-8972</identifier><identifier>EISSN: 1029-0389</identifier><identifier>DOI: 10.1080/00958979808230441</identifier><language>eng</language><publisher>Taylor & Francis Group</publisher><subject>binuclear complex ; cadmium ; polyazamacrocycle ; X-ray structure</subject><ispartof>Journal of coordination chemistry, 1998-04, Vol.43 (4), p.281-288</ispartof><rights>Copyright Taylor & Francis Group, LLC 1998</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c344t-a0fe6bc7832eac04ffdf7c244f4388c1731c92a66f6a7a0f5e6969e8f76682953</citedby><cites>FETCH-LOGICAL-c344t-a0fe6bc7832eac04ffdf7c244f4388c1731c92a66f6a7a0f5e6969e8f76682953</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Xu, Xin-You</creatorcontrib><creatorcontrib>Wang, Zhi-Lin</creatorcontrib><creatorcontrib>Luo, Qin-Hui</creatorcontrib><creatorcontrib>Shen, Meng-Chang</creatorcontrib><creatorcontrib>Zhou, Xiang-Ge</creatorcontrib><creatorcontrib>Zhou, Zhong-Yuan</creatorcontrib><title>Synthesis and x-ray crystal structure of a 24-membered macrocyclic binuclear cadmium(ii) complex with pendant arms</title><title>Journal of coordination chemistry</title><description>A new binuclear cadmium(II) macrocyclic complex has been synthesized by [2 + 2] Schiff base condensation of tris(2-aminoethyl)amine (tren) with sodium 2, 6-diformyl-4-bromo-phenolate (sdbp) in the presence of Cd
2+
ion. The crystal structure of the complex [Cd
2
L](ClO
4
)
2
0.5CH
3
OH has been determined by X-ray methods. Crystals are mono-clinic, space group P2
1
/c with a = 11.633(15), b = 16.370(2), c = 21.193(2) Å, β = 96.121(12)°, Z= 4, V= 4013.0(8) Å
3
, F(000) = 2180, Dc., = 1.841 g cm
−3
, μ = 32.46 cm
−1
, R = 0.049, R
w
= 0.069. Two cadmium(II) ions are bridged by two μ
2
-phenoxy oxygen atoms. Each cadmium lies in a N
4
O
2
coordination environment. Coordination geometry around Cd(II) is a capped trigonal bipyramid. Coordination of phenoxy oxygens and terminal amino groups enhances the stability of the complex.</description><subject>binuclear complex</subject><subject>cadmium</subject><subject>polyazamacrocycle</subject><subject>X-ray structure</subject><issn>0095-8972</issn><issn>1029-0389</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><recordid>eNqFkEtLAzEUhYMoWKs_wF2WuhjNq3mAGym-oOBCXQ-3mYRGJjMlSWnn3zul7oq4uotzvnMuB6FrSu4o0eSeEDPTRhlNNONECHqCJpQwUxGuzSma7PVqNLBzdJHzNyGUc6YmKH0MXVm5HDKGrsG7KsGAbRpygRbnkja2bJLDvceAmaiii0uXXIMj2NTbwbbB4mXoNrZ1kLCFJoZNvAnhFts-rlu3w9tQVnjtuga6giHFfInOPLTZXf3eKfp6fvqcv1aL95e3-eOislyIUgHxTi6t0pw5sER433hlmRBecK0tVZxaw0BKL0GN5pmTRhqnvZJSMzPjU0QPueOnOSfn63UKEdJQU1LvR6uPRhsZdWBC5_sUYduntqkLDG2ffILOhnxM1WVXRvLhX5L_XfwDkXyGUQ</recordid><startdate>19980401</startdate><enddate>19980401</enddate><creator>Xu, Xin-You</creator><creator>Wang, Zhi-Lin</creator><creator>Luo, Qin-Hui</creator><creator>Shen, Meng-Chang</creator><creator>Zhou, Xiang-Ge</creator><creator>Zhou, Zhong-Yuan</creator><general>Taylor & Francis Group</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19980401</creationdate><title>Synthesis and x-ray crystal structure of a 24-membered macrocyclic binuclear cadmium(ii) complex with pendant arms</title><author>Xu, Xin-You ; Wang, Zhi-Lin ; Luo, Qin-Hui ; Shen, Meng-Chang ; Zhou, Xiang-Ge ; Zhou, Zhong-Yuan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c344t-a0fe6bc7832eac04ffdf7c244f4388c1731c92a66f6a7a0f5e6969e8f76682953</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1998</creationdate><topic>binuclear complex</topic><topic>cadmium</topic><topic>polyazamacrocycle</topic><topic>X-ray structure</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xu, Xin-You</creatorcontrib><creatorcontrib>Wang, Zhi-Lin</creatorcontrib><creatorcontrib>Luo, Qin-Hui</creatorcontrib><creatorcontrib>Shen, Meng-Chang</creatorcontrib><creatorcontrib>Zhou, Xiang-Ge</creatorcontrib><creatorcontrib>Zhou, Zhong-Yuan</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xu, Xin-You</au><au>Wang, Zhi-Lin</au><au>Luo, Qin-Hui</au><au>Shen, Meng-Chang</au><au>Zhou, Xiang-Ge</au><au>Zhou, Zhong-Yuan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and x-ray crystal structure of a 24-membered macrocyclic binuclear cadmium(ii) complex with pendant arms</atitle><jtitle>Journal of coordination chemistry</jtitle><date>1998-04-01</date><risdate>1998</risdate><volume>43</volume><issue>4</issue><spage>281</spage><epage>288</epage><pages>281-288</pages><issn>0095-8972</issn><eissn>1029-0389</eissn><abstract>A new binuclear cadmium(II) macrocyclic complex has been synthesized by [2 + 2] Schiff base condensation of tris(2-aminoethyl)amine (tren) with sodium 2, 6-diformyl-4-bromo-phenolate (sdbp) in the presence of Cd
2+
ion. The crystal structure of the complex [Cd
2
L](ClO
4
)
2
0.5CH
3
OH has been determined by X-ray methods. Crystals are mono-clinic, space group P2
1
/c with a = 11.633(15), b = 16.370(2), c = 21.193(2) Å, β = 96.121(12)°, Z= 4, V= 4013.0(8) Å
3
, F(000) = 2180, Dc., = 1.841 g cm
−3
, μ = 32.46 cm
−1
, R = 0.049, R
w
= 0.069. Two cadmium(II) ions are bridged by two μ
2
-phenoxy oxygen atoms. Each cadmium lies in a N
4
O
2
coordination environment. Coordination geometry around Cd(II) is a capped trigonal bipyramid. Coordination of phenoxy oxygens and terminal amino groups enhances the stability of the complex.</abstract><pub>Taylor & Francis Group</pub><doi>10.1080/00958979808230441</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0095-8972 |
| ispartof | Journal of coordination chemistry, 1998-04, Vol.43 (4), p.281-288 |
| issn | 0095-8972 1029-0389 |
| language | eng |
| recordid | cdi_crossref_primary_10_1080_00958979808230441 |
| source | Taylor and Francis Science and Technology Collection |
| subjects | binuclear complex cadmium polyazamacrocycle X-ray structure |
| title | Synthesis and x-ray crystal structure of a 24-membered macrocyclic binuclear cadmium(ii) complex with pendant arms |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-07T13%3A54%3A44IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref_infor&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20and%20x-ray%20crystal%20structure%20of%20a%2024-membered%20macrocyclic%20binuclear%20cadmium(ii)%20complex%20with%20pendant%20arms&rft.jtitle=Journal%20of%20coordination%20chemistry&rft.au=Xu,%20Xin-You&rft.date=1998-04-01&rft.volume=43&rft.issue=4&rft.spage=281&rft.epage=288&rft.pages=281-288&rft.issn=0095-8972&rft.eissn=1029-0389&rft_id=info:doi/10.1080/00958979808230441&rft_dat=%3Ccrossref_infor%3E10_1080_00958979808230441%3C/crossref_infor%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c344t-a0fe6bc7832eac04ffdf7c244f4388c1731c92a66f6a7a0f5e6969e8f76682953%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |