Loading…

ISFME extraction of As species from some real water samples using an imidazolium-based task-specific ionic liquid (TSIL): Synthesis and characterization

To determine of arsenic species in real water samples using electrothermal atomic absorption spectrometry, a high-performance in-situ solvent formation microextraction technique has been developed using homogenous liquid - liquid microextraction concepts. The developed method was based on the use of...

Full description

Saved in:
Bibliographic Details
Published in:Separation science and technology 2024-03, Vol.59 (4), p.580-591
Main Authors: Hosseini, Mehdi, Khoshfetrat, Seyyed Mehdi, Panahimehr, Mohammad, Rezaei, Aram
Format: Article
Language:English
Subjects:
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c338t-e6b9c15a71526f7d913ae6e8727b524ec22e91e43bc1f173323ee85a334a8d493
cites cdi_FETCH-LOGICAL-c338t-e6b9c15a71526f7d913ae6e8727b524ec22e91e43bc1f173323ee85a334a8d493
container_end_page 591
container_issue 4
container_start_page 580
container_title Separation science and technology
container_volume 59
creator Hosseini, Mehdi
Khoshfetrat, Seyyed Mehdi
Panahimehr, Mohammad
Rezaei, Aram
description To determine of arsenic species in real water samples using electrothermal atomic absorption spectrometry, a high-performance in-situ solvent formation microextraction technique has been developed using homogenous liquid - liquid microextraction concepts. The developed method was based on the use of a synthesized imidazolium-based ionic liquid (IL) modified with ammonium pyrrolidine dithiocarbamate as a task-specific ionic liquid (TSIL), which was chelated with As(III) and then converted to a hydrophobic IL using ammonium hexafluorophosphate in anion exchange reactions. As(V) was reduced to As(III), using a satisfied reducing agent, and the total amount of As was analyzed using ETAAS. TSIL acts simultaneously as an extracting solvent and a chelating agent. The characterization of the synthesized TSIL was performed using 13 CNMR and FTIR analyses. When optimal conditions were met, linear dynamic ranges of 0.5-50 µg/L and 0.5-20 µg/L were obtained in the determination of As(III) and total As, respectively. The limits of detection (LOD) and quantitation (LOQ) were determined to be 0.021 µg/Land 0.064 µg/L for the determination of As(III) (for concentration 20 µg/L), respectively, and the standard deviation (RSD%, n = 7) was 2.0%. To evaluate the validity of the method, it was successfully applied for As species determination in different real water samples.
doi_str_mv 10.1080/01496395.2024.2328678
format article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1080_01496395_2024_2328678</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3037753047</sourcerecordid><originalsourceid>FETCH-LOGICAL-c338t-e6b9c15a71526f7d913ae6e8727b524ec22e91e43bc1f173323ee85a334a8d493</originalsourceid><addsrcrecordid>eNp9kc9O3DAQxq2qlbqFPkIlS73QQ7b-E8cJpyIE7UqLelh6tmadcTFN4sVOBMuT8Lg4XbhymTnMN7_5Rh8hXzhbclaz74yXTSUbtRRMlEshRV3p-h1ZcCVYobQq35PFrClm0UfyKaVbxlitmmZBnlaby6sLig9jBDv6MNDg6FmiaYfWY6Iuhp6m0CONCB29hxEjTdDvujyckh_-Uhio730Lj6HzU19sIWFLR0j_iv8Q5y3N3Fw7fzf5lp5cb1brb6d0sx_GG0w-ZUJL7Q3MDjD6R5h9HJMPDrqEn1_6EflzeXF9_qtY__65Oj9bF1bKeiyw2jaWK9D52crptuESsMJaC71VokQrBDYcS7m13HEtpZCItQIpS6jbspFH5OuBu4vhbsI0mtswxSGfNJJJrZVkpc4qdVDZGFKK6Mwu-h7i3nBm5hDMawhmDsG8hJD3fhz2_OBC7OE-xK41I-y7EF2Ewfp85m3EMzFXj4w</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>3037753047</pqid></control><display><type>article</type><title>ISFME extraction of As species from some real water samples using an imidazolium-based task-specific ionic liquid (TSIL): Synthesis and characterization</title><source>Taylor and Francis Science and Technology Collection</source><creator>Hosseini, Mehdi ; Khoshfetrat, Seyyed Mehdi ; Panahimehr, Mohammad ; Rezaei, Aram</creator><creatorcontrib>Hosseini, Mehdi ; Khoshfetrat, Seyyed Mehdi ; Panahimehr, Mohammad ; Rezaei, Aram</creatorcontrib><description>To determine of arsenic species in real water samples using electrothermal atomic absorption spectrometry, a high-performance in-situ solvent formation microextraction technique has been developed using homogenous liquid - liquid microextraction concepts. The developed method was based on the use of a synthesized imidazolium-based ionic liquid (IL) modified with ammonium pyrrolidine dithiocarbamate as a task-specific ionic liquid (TSIL), which was chelated with As(III) and then converted to a hydrophobic IL using ammonium hexafluorophosphate in anion exchange reactions. As(V) was reduced to As(III), using a satisfied reducing agent, and the total amount of As was analyzed using ETAAS. TSIL acts simultaneously as an extracting solvent and a chelating agent. The characterization of the synthesized TSIL was performed using 13 CNMR and FTIR analyses. When optimal conditions were met, linear dynamic ranges of 0.5-50 µg/L and 0.5-20 µg/L were obtained in the determination of As(III) and total As, respectively. The limits of detection (LOD) and quantitation (LOQ) were determined to be 0.021 µg/Land 0.064 µg/L for the determination of As(III) (for concentration 20 µg/L), respectively, and the standard deviation (RSD%, n = 7) was 2.0%. To evaluate the validity of the method, it was successfully applied for As species determination in different real water samples.</description><identifier>ISSN: 0149-6395</identifier><identifier>EISSN: 1520-5754</identifier><identifier>DOI: 10.1080/01496395.2024.2328678</identifier><language>eng</language><publisher>Abingdon: Taylor &amp; Francis</publisher><subject>Absorption spectroscopy ; Ammonium ; Ammonium compounds ; Anion exchange ; Anion exchanging ; Anions ; Arsenic ; arsenic speciation ; Atomic absorption spectroscopy ; Chelates ; Chelating agents ; Chelation ; electrothermal atomic absorption ; Hydrophobicity ; Ionic liquids ; Pyrrolidine ; Pyrrolidine dithiocarbamate ; Reducing agents ; solvent-based microextraction ; Solvents ; Spectral analysis ; Spectrometry ; Synthesis ; synthesis and characterization ; Task-specific ionic liquid ; Water analysis ; Water sampling</subject><ispartof>Separation science and technology, 2024-03, Vol.59 (4), p.580-591</ispartof><rights>2024 Taylor &amp; Francis Group, LLC 2024</rights><rights>2024 Taylor &amp; Francis Group, LLC</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c338t-e6b9c15a71526f7d913ae6e8727b524ec22e91e43bc1f173323ee85a334a8d493</citedby><cites>FETCH-LOGICAL-c338t-e6b9c15a71526f7d913ae6e8727b524ec22e91e43bc1f173323ee85a334a8d493</cites><orcidid>0000-0001-5999-5178</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Hosseini, Mehdi</creatorcontrib><creatorcontrib>Khoshfetrat, Seyyed Mehdi</creatorcontrib><creatorcontrib>Panahimehr, Mohammad</creatorcontrib><creatorcontrib>Rezaei, Aram</creatorcontrib><title>ISFME extraction of As species from some real water samples using an imidazolium-based task-specific ionic liquid (TSIL): Synthesis and characterization</title><title>Separation science and technology</title><description>To determine of arsenic species in real water samples using electrothermal atomic absorption spectrometry, a high-performance in-situ solvent formation microextraction technique has been developed using homogenous liquid - liquid microextraction concepts. The developed method was based on the use of a synthesized imidazolium-based ionic liquid (IL) modified with ammonium pyrrolidine dithiocarbamate as a task-specific ionic liquid (TSIL), which was chelated with As(III) and then converted to a hydrophobic IL using ammonium hexafluorophosphate in anion exchange reactions. As(V) was reduced to As(III), using a satisfied reducing agent, and the total amount of As was analyzed using ETAAS. TSIL acts simultaneously as an extracting solvent and a chelating agent. The characterization of the synthesized TSIL was performed using 13 CNMR and FTIR analyses. When optimal conditions were met, linear dynamic ranges of 0.5-50 µg/L and 0.5-20 µg/L were obtained in the determination of As(III) and total As, respectively. The limits of detection (LOD) and quantitation (LOQ) were determined to be 0.021 µg/Land 0.064 µg/L for the determination of As(III) (for concentration 20 µg/L), respectively, and the standard deviation (RSD%, n = 7) was 2.0%. To evaluate the validity of the method, it was successfully applied for As species determination in different real water samples.</description><subject>Absorption spectroscopy</subject><subject>Ammonium</subject><subject>Ammonium compounds</subject><subject>Anion exchange</subject><subject>Anion exchanging</subject><subject>Anions</subject><subject>Arsenic</subject><subject>arsenic speciation</subject><subject>Atomic absorption spectroscopy</subject><subject>Chelates</subject><subject>Chelating agents</subject><subject>Chelation</subject><subject>electrothermal atomic absorption</subject><subject>Hydrophobicity</subject><subject>Ionic liquids</subject><subject>Pyrrolidine</subject><subject>Pyrrolidine dithiocarbamate</subject><subject>Reducing agents</subject><subject>solvent-based microextraction</subject><subject>Solvents</subject><subject>Spectral analysis</subject><subject>Spectrometry</subject><subject>Synthesis</subject><subject>synthesis and characterization</subject><subject>Task-specific ionic liquid</subject><subject>Water analysis</subject><subject>Water sampling</subject><issn>0149-6395</issn><issn>1520-5754</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2024</creationdate><recordtype>article</recordtype><recordid>eNp9kc9O3DAQxq2qlbqFPkIlS73QQ7b-E8cJpyIE7UqLelh6tmadcTFN4sVOBMuT8Lg4XbhymTnMN7_5Rh8hXzhbclaz74yXTSUbtRRMlEshRV3p-h1ZcCVYobQq35PFrClm0UfyKaVbxlitmmZBnlaby6sLig9jBDv6MNDg6FmiaYfWY6Iuhp6m0CONCB29hxEjTdDvujyckh_-Uhio730Lj6HzU19sIWFLR0j_iv8Q5y3N3Fw7fzf5lp5cb1brb6d0sx_GG0w-ZUJL7Q3MDjD6R5h9HJMPDrqEn1_6EflzeXF9_qtY__65Oj9bF1bKeiyw2jaWK9D52crptuESsMJaC71VokQrBDYcS7m13HEtpZCItQIpS6jbspFH5OuBu4vhbsI0mtswxSGfNJJJrZVkpc4qdVDZGFKK6Mwu-h7i3nBm5hDMawhmDsG8hJD3fhz2_OBC7OE-xK41I-y7EF2Ewfp85m3EMzFXj4w</recordid><startdate>20240303</startdate><enddate>20240303</enddate><creator>Hosseini, Mehdi</creator><creator>Khoshfetrat, Seyyed Mehdi</creator><creator>Panahimehr, Mohammad</creator><creator>Rezaei, Aram</creator><general>Taylor &amp; Francis</general><general>Taylor &amp; Francis Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QH</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7T7</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>7UA</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F1W</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>H97</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L.G</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope><orcidid>https://orcid.org/0000-0001-5999-5178</orcidid></search><sort><creationdate>20240303</creationdate><title>ISFME extraction of As species from some real water samples using an imidazolium-based task-specific ionic liquid (TSIL): Synthesis and characterization</title><author>Hosseini, Mehdi ; Khoshfetrat, Seyyed Mehdi ; Panahimehr, Mohammad ; Rezaei, Aram</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c338t-e6b9c15a71526f7d913ae6e8727b524ec22e91e43bc1f173323ee85a334a8d493</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2024</creationdate><topic>Absorption spectroscopy</topic><topic>Ammonium</topic><topic>Ammonium compounds</topic><topic>Anion exchange</topic><topic>Anion exchanging</topic><topic>Anions</topic><topic>Arsenic</topic><topic>arsenic speciation</topic><topic>Atomic absorption spectroscopy</topic><topic>Chelates</topic><topic>Chelating agents</topic><topic>Chelation</topic><topic>electrothermal atomic absorption</topic><topic>Hydrophobicity</topic><topic>Ionic liquids</topic><topic>Pyrrolidine</topic><topic>Pyrrolidine dithiocarbamate</topic><topic>Reducing agents</topic><topic>solvent-based microextraction</topic><topic>Solvents</topic><topic>Spectral analysis</topic><topic>Spectrometry</topic><topic>Synthesis</topic><topic>synthesis and characterization</topic><topic>Task-specific ionic liquid</topic><topic>Water analysis</topic><topic>Water sampling</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hosseini, Mehdi</creatorcontrib><creatorcontrib>Khoshfetrat, Seyyed Mehdi</creatorcontrib><creatorcontrib>Panahimehr, Mohammad</creatorcontrib><creatorcontrib>Rezaei, Aram</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Aqualine</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics &amp; Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Materials Business File</collection><collection>Mechanical &amp; Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Water Resources Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>ANTE: Abstracts in New Technology &amp; Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>Aquatic Science &amp; Fisheries Abstracts (ASFA) 3: Aquatic Pollution &amp; Environmental Quality</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Aquatic Science &amp; Fisheries Abstracts (ASFA) Professional</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts – Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Separation science and technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hosseini, Mehdi</au><au>Khoshfetrat, Seyyed Mehdi</au><au>Panahimehr, Mohammad</au><au>Rezaei, Aram</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>ISFME extraction of As species from some real water samples using an imidazolium-based task-specific ionic liquid (TSIL): Synthesis and characterization</atitle><jtitle>Separation science and technology</jtitle><date>2024-03-03</date><risdate>2024</risdate><volume>59</volume><issue>4</issue><spage>580</spage><epage>591</epage><pages>580-591</pages><issn>0149-6395</issn><eissn>1520-5754</eissn><abstract>To determine of arsenic species in real water samples using electrothermal atomic absorption spectrometry, a high-performance in-situ solvent formation microextraction technique has been developed using homogenous liquid - liquid microextraction concepts. The developed method was based on the use of a synthesized imidazolium-based ionic liquid (IL) modified with ammonium pyrrolidine dithiocarbamate as a task-specific ionic liquid (TSIL), which was chelated with As(III) and then converted to a hydrophobic IL using ammonium hexafluorophosphate in anion exchange reactions. As(V) was reduced to As(III), using a satisfied reducing agent, and the total amount of As was analyzed using ETAAS. TSIL acts simultaneously as an extracting solvent and a chelating agent. The characterization of the synthesized TSIL was performed using 13 CNMR and FTIR analyses. When optimal conditions were met, linear dynamic ranges of 0.5-50 µg/L and 0.5-20 µg/L were obtained in the determination of As(III) and total As, respectively. The limits of detection (LOD) and quantitation (LOQ) were determined to be 0.021 µg/Land 0.064 µg/L for the determination of As(III) (for concentration 20 µg/L), respectively, and the standard deviation (RSD%, n = 7) was 2.0%. To evaluate the validity of the method, it was successfully applied for As species determination in different real water samples.</abstract><cop>Abingdon</cop><pub>Taylor &amp; Francis</pub><doi>10.1080/01496395.2024.2328678</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0001-5999-5178</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 0149-6395
ispartof Separation science and technology, 2024-03, Vol.59 (4), p.580-591
issn 0149-6395
1520-5754
language eng
recordid cdi_crossref_primary_10_1080_01496395_2024_2328678
source Taylor and Francis Science and Technology Collection
subjects Absorption spectroscopy
Ammonium
Ammonium compounds
Anion exchange
Anion exchanging
Anions
Arsenic
arsenic speciation
Atomic absorption spectroscopy
Chelates
Chelating agents
Chelation
electrothermal atomic absorption
Hydrophobicity
Ionic liquids
Pyrrolidine
Pyrrolidine dithiocarbamate
Reducing agents
solvent-based microextraction
Solvents
Spectral analysis
Spectrometry
Synthesis
synthesis and characterization
Task-specific ionic liquid
Water analysis
Water sampling
title ISFME extraction of As species from some real water samples using an imidazolium-based task-specific ionic liquid (TSIL): Synthesis and characterization
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-06T20%3A34%3A01IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=ISFME%20extraction%20of%20As%20species%20from%20some%20real%20water%20samples%20using%20an%20imidazolium-based%20task-specific%20ionic%20liquid%20(TSIL):%20Synthesis%20and%20characterization&rft.jtitle=Separation%20science%20and%20technology&rft.au=Hosseini,%20Mehdi&rft.date=2024-03-03&rft.volume=59&rft.issue=4&rft.spage=580&rft.epage=591&rft.pages=580-591&rft.issn=0149-6395&rft.eissn=1520-5754&rft_id=info:doi/10.1080/01496395.2024.2328678&rft_dat=%3Cproquest_cross%3E3037753047%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c338t-e6b9c15a71526f7d913ae6e8727b524ec22e91e43bc1f173323ee85a334a8d493%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=3037753047&rft_id=info:pmid/&rfr_iscdi=true