Liquid crystal droplets under extreme confinement probed by a multiscale simulation approach

• Published in: Liquid crystals 2021-10, Vol.48 (13), p.1827-1839
• Main Authors: Sumer, Zeynep, Fernandez, F. Anibal, Striolo, Alberto
• Format: Article
• Language: English
• ISSN: 0267-8292; 1366-5855
• DOI: 10.1080/02678292.2021.1902581

In this work, we computationally investigate liquid crystal (LC) droplets in the size range 0.03-1 μm, confined within shells of combined anchoring conditions. Two different types of surface were defined to promote homeotropic and planar degenerate anchoring, respectively. We identified the LC behaviour within the nanoscale droplets using a bespoke multiscale simulation approach. To study 30 nm droplets, we used coarse grained simulations within the dissipative particle dynamics formalism; to study 0.1 μm and larger droplets, we used a finite element method based on the Landau-de Gennes theory. Good agreement between the two methods was observed in our prior analysis and was confirmed in the present work. We explicitly study droplets of size 0.1 and 1 μm by using continuum mechanics calculations. Our results for the largest droplet are consistent with those available in the literature, suggesting that the extension to smaller droplets presented here is realistic, and therefore can be helpful for innovations in which device intensification could be achieved using LC nanodroplets.