Measurement of size-dependent dynamic shape factors of quartz particles in two flow regimes

• Published in: Aerosol science and technology 2016-08, Vol.50 (8), p.870-879
• Main Authors: Alexander, J. M., Bell, D. M., Imre, D., Kleiber, P. D., Grassian, V. H., Zelenyuk, A.
• Format: Article
• Language: English
• Subjects: Aerosol particles; Aerosol research; Aerosols; Analyzers; Atmospheric models; Composition effects; Dust particles; Dynamic tests; Dynamics; Environmental Molecular Sciences Laboratory; Equivalence; Jian Wang; Mass spectrometry; Mathematical models; Mobility; Molecular chains; Particle mass; Particle shape; Particle size; Quartz; Shape factor; Silica; size-dependent shape of quartz particles; Transition flow
• ISSN: 0278-6826; 1521-7388
• DOI: 10.1080/02786826.2016.1200006

Understanding and modeling the behavior of quartz dust particles, commonly found in the atmosphere, requires knowledge of many relevant particle properties, including particle shape. This study uses a single particle mass spectrometer, a differential mobility analyzer, and an aerosol particle mass analyzer to measure quartz aerosol particles mobility (d m ), vacuum aerodynamic, and volume equivalent diameters, mass, composition, effective density, and dynamic shape factor as a function of particle size, in both the free molecular and transition flow regimes. The results clearly demonstrate that dynamic shape factors can vary significantly as a function of particle size. For the quartz samples studied here, the dynamic shape factors increase with size, indicating that larger particles are significantly more aspherical than smaller particles. In addition, dynamic shape factors measured in the free-molecular (χ v ) and transition (χ t ) flow regimes can be significantly different, and these differences vary with the size of the quartz particles. For quartz, χ v of small (d m < 200 nm) particles is 1.25, while χ v of larger particles (d m ∼ 440 nm) is 1.6, with a continuously increasing trend with particle size. In contrast, χ t of small particles starts at 1.1 increasing slowly to 1.34 for 550 nm diameter particles. The multidimensional particle characterization approach used here goes beyond determination of average properties for each size, to provide additional information about how the particle dynamic shape factor may vary even for particles with the same mass and volume equivalent diameter. © 2016 American Association for Aerosol Research