A Facile, One-Step Conversion of 6-O-Trityl and 6-O-TBDMS Monosaccharides into the Corresponding Formate Esters

A convenient method has been developed for a facile and high-yield conversion of 6-O-tert-butyldimethylsilyl and 6-O-trityl protected monosaccharides to their formate esters, which may serve as useful intermediates for the replacement of the primary hydroxyl group of sugars by other functional group...

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Bibliographic Details
Published in:Journal of carbohydrate chemistry 2006-08, Vol.25 (6), p.441-450
Main Authors: Komiotis, Dimitri, Agelis, George, Manta, Stella, Tzioumaki, Niki, Tsoukala, Evangelia, Antonakis, Kostas
Format: Article
Language:English
Subjects:
Formate ester
Formic acid
O-branched chain reactions
tert-Butyldimethylsilyl
Trityl
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Summary:A convenient method has been developed for a facile and high-yield conversion of 6-O-tert-butyldimethylsilyl and 6-O-trityl protected monosaccharides to their formate esters, which may serve as useful intermediates for the replacement of the primary hydroxyl group of sugars by other functional groups.
ISSN:0732-8303
1532-2327
DOI:10.1080/07328300600859668