Binary phase diagram series: 1,3,3-trinitroazetidine (TNAZ)/1,3,5-trinitrobenzene (TNB)

The binary phase diagram for the 1,3,3-trinitroazetidine (TNAZ)/1,3,5-Trinitrobenzene (TNB) system has been predicted computationally and determined experimentally. Mixtures exhibit the thermal characteristics associated with a simple binary eutectic system affected by both non-ideal behavior of the...

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Bibliographic Details
Published in:Journal of energetic materials 2000-12, Vol.18 (4), p.241-273
Main Authors: McKenney, R. L., Stevens, W. E.
Format: Article
Language:English
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Summary:The binary phase diagram for the 1,3,3-trinitroazetidine (TNAZ)/1,3,5-Trinitrobenzene (TNB) system has been predicted computationally and determined experimentally. Mixtures exhibit the thermal characteristics associated with a simple binary eutectic system affected by both non-ideal behavior of the two components and observable polymorphism associated only with TNB. Experimental eutectic temperature/composition (°C/mol percent TNAZ) values in the binary mixtures believed to contain one or more of the TNB polymorphic modifications, I, III and IV, are 68.4/53.4, 63.6/47.8 and 62.0/45.6, respectively.
ISSN:0737-0652
1545-8822
DOI:10.1080/07370650008219112