Liquid Chromatography of Polymers at the Exclusion - Adsorption Transition Point: Physicochemical Interpretation

This paper deals with liquid chromatography of polymers at the exclusion-adsorption transition point (LC EATP). In order to better understand and define this specific elution mode, all polymer chains with the same chemical structure are eluted at the identical retention time whatever their molar mas...

Full description

Saved in:
Bibliographic Details
Published in:International journal of polymer analysis & characterization 2001, Vol.6 (1-2), p.123-145
Main Authors: Baran, Katia, Laugier, Serge, Cramail, Henri
Format: Article
Language:English
Subjects:
Critical conditions
Liquid chromatography
Polymer/absorbent interactions
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c344t-ae6c0c32b93d02d82dba37eac72bad8017d1b059b51af01a2b03a7a75540f03e3
cites cdi_FETCH-LOGICAL-c344t-ae6c0c32b93d02d82dba37eac72bad8017d1b059b51af01a2b03a7a75540f03e3
container_end_page 145
container_issue 1-2
container_start_page 123
container_title International journal of polymer analysis & characterization
container_volume 6
creator Baran, Katia
Laugier, Serge
Cramail, Henri
description This paper deals with liquid chromatography of polymers at the exclusion-adsorption transition point (LC EATP). In order to better understand and define this specific elution mode, all polymer chains with the same chemical structure are eluted at the identical retention time whatever their molar mass, a physicochemical study dealing with solution properties of polymers was undertaken. A correlation between polystyrene dimensions and this chromatographic mode was attempted by viscometry and light scattering measurements. The influence of temperature was also studied. It was demonstrated that EATP is obtained for specific values of polymer/adsorbent interactions, for a given eluent desorli/adsorli, and for a "critical polarity" of the eluent.
doi_str_mv 10.1080/10236660008034654
format article
fullrecord <record><control><sourceid>crossref_infor</sourceid><recordid>TN_cdi_crossref_primary_10_1080_10236660008034654</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1080_10236660008034654</sourcerecordid><originalsourceid>FETCH-LOGICAL-c344t-ae6c0c32b93d02d82dba37eac72bad8017d1b059b51af01a2b03a7a75540f03e3</originalsourceid><addsrcrecordid>eNqFkE1OwzAQhS0EEqVwAHa-QGBs56dFbKqqlEqV6KJI7KKJ7RCjJA62K5rbk1J2FWI172neN6MZQm4Z3DGYwD0DLtI0BRiMiNMkPiMjlqQiSkTMzgc99KMh8HZJrrz_AOCMQTwi3dp87oyi88rZBoN9d9hVPbUl3di6b7TzFAMNlaaLvax33tiWRnSmvHVdOJitw9abH7mxpg0PdFP13kgrK90YiTVdtUG7zumAh9Q1uSix9vrmt47J69NiO3-O1i_L1Xy2jqSI4xChTiVIwYupUMDVhKsCRaZRZrxANQGWKVZAMi0ShiUw5AUIzDBLkhhKEFqMCTvOlc5673SZd8406PqcQX54WX7ysoHJjoxpS-sa_LKuVnnAvrauHO6Uxp9SediHgXz8lxR_L_4GT6uGUA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Liquid Chromatography of Polymers at the Exclusion - Adsorption Transition Point: Physicochemical Interpretation</title><source>Taylor and Francis Science and Technology Collection</source><creator>Baran, Katia ; Laugier, Serge ; Cramail, Henri</creator><creatorcontrib>Baran, Katia ; Laugier, Serge ; Cramail, Henri</creatorcontrib><description>This paper deals with liquid chromatography of polymers at the exclusion-adsorption transition point (LC EATP). In order to better understand and define this specific elution mode, all polymer chains with the same chemical structure are eluted at the identical retention time whatever their molar mass, a physicochemical study dealing with solution properties of polymers was undertaken. A correlation between polystyrene dimensions and this chromatographic mode was attempted by viscometry and light scattering measurements. The influence of temperature was also studied. It was demonstrated that EATP is obtained for specific values of polymer/adsorbent interactions, for a given eluent desorli/adsorli, and for a "critical polarity" of the eluent.</description><identifier>ISSN: 1023-666X</identifier><identifier>EISSN: 1563-5341</identifier><identifier>DOI: 10.1080/10236660008034654</identifier><language>eng</language><publisher>Taylor &amp; Francis Group</publisher><subject>Critical conditions ; Liquid chromatography ; Polymer/absorbent interactions</subject><ispartof>International journal of polymer analysis &amp; characterization, 2001, Vol.6 (1-2), p.123-145</ispartof><rights>Copyright Taylor &amp; Francis Group, LLC 2001</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c344t-ae6c0c32b93d02d82dba37eac72bad8017d1b059b51af01a2b03a7a75540f03e3</citedby><cites>FETCH-LOGICAL-c344t-ae6c0c32b93d02d82dba37eac72bad8017d1b059b51af01a2b03a7a75540f03e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,4024,27923,27924,27925</link.rule.ids></links><search><creatorcontrib>Baran, Katia</creatorcontrib><creatorcontrib>Laugier, Serge</creatorcontrib><creatorcontrib>Cramail, Henri</creatorcontrib><title>Liquid Chromatography of Polymers at the Exclusion - Adsorption Transition Point: Physicochemical Interpretation</title><title>International journal of polymer analysis &amp; characterization</title><description>This paper deals with liquid chromatography of polymers at the exclusion-adsorption transition point (LC EATP). In order to better understand and define this specific elution mode, all polymer chains with the same chemical structure are eluted at the identical retention time whatever their molar mass, a physicochemical study dealing with solution properties of polymers was undertaken. A correlation between polystyrene dimensions and this chromatographic mode was attempted by viscometry and light scattering measurements. The influence of temperature was also studied. It was demonstrated that EATP is obtained for specific values of polymer/adsorbent interactions, for a given eluent desorli/adsorli, and for a "critical polarity" of the eluent.</description><subject>Critical conditions</subject><subject>Liquid chromatography</subject><subject>Polymer/absorbent interactions</subject><issn>1023-666X</issn><issn>1563-5341</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><recordid>eNqFkE1OwzAQhS0EEqVwAHa-QGBs56dFbKqqlEqV6KJI7KKJ7RCjJA62K5rbk1J2FWI172neN6MZQm4Z3DGYwD0DLtI0BRiMiNMkPiMjlqQiSkTMzgc99KMh8HZJrrz_AOCMQTwi3dp87oyi88rZBoN9d9hVPbUl3di6b7TzFAMNlaaLvax33tiWRnSmvHVdOJitw9abH7mxpg0PdFP13kgrK90YiTVdtUG7zumAh9Q1uSix9vrmt47J69NiO3-O1i_L1Xy2jqSI4xChTiVIwYupUMDVhKsCRaZRZrxANQGWKVZAMi0ShiUw5AUIzDBLkhhKEFqMCTvOlc5673SZd8406PqcQX54WX7ysoHJjoxpS-sa_LKuVnnAvrauHO6Uxp9SediHgXz8lxR_L_4GT6uGUA</recordid><startdate>2001</startdate><enddate>2001</enddate><creator>Baran, Katia</creator><creator>Laugier, Serge</creator><creator>Cramail, Henri</creator><general>Taylor &amp; Francis Group</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2001</creationdate><title>Liquid Chromatography of Polymers at the Exclusion - Adsorption Transition Point: Physicochemical Interpretation</title><author>Baran, Katia ; Laugier, Serge ; Cramail, Henri</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c344t-ae6c0c32b93d02d82dba37eac72bad8017d1b059b51af01a2b03a7a75540f03e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2001</creationdate><topic>Critical conditions</topic><topic>Liquid chromatography</topic><topic>Polymer/absorbent interactions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Baran, Katia</creatorcontrib><creatorcontrib>Laugier, Serge</creatorcontrib><creatorcontrib>Cramail, Henri</creatorcontrib><collection>CrossRef</collection><jtitle>International journal of polymer analysis &amp; characterization</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Baran, Katia</au><au>Laugier, Serge</au><au>Cramail, Henri</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Liquid Chromatography of Polymers at the Exclusion - Adsorption Transition Point: Physicochemical Interpretation</atitle><jtitle>International journal of polymer analysis &amp; characterization</jtitle><date>2001</date><risdate>2001</risdate><volume>6</volume><issue>1-2</issue><spage>123</spage><epage>145</epage><pages>123-145</pages><issn>1023-666X</issn><eissn>1563-5341</eissn><abstract>This paper deals with liquid chromatography of polymers at the exclusion-adsorption transition point (LC EATP). In order to better understand and define this specific elution mode, all polymer chains with the same chemical structure are eluted at the identical retention time whatever their molar mass, a physicochemical study dealing with solution properties of polymers was undertaken. A correlation between polystyrene dimensions and this chromatographic mode was attempted by viscometry and light scattering measurements. The influence of temperature was also studied. It was demonstrated that EATP is obtained for specific values of polymer/adsorbent interactions, for a given eluent desorli/adsorli, and for a "critical polarity" of the eluent.</abstract><pub>Taylor &amp; Francis Group</pub><doi>10.1080/10236660008034654</doi><tpages>23</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1023-666X
ispartof International journal of polymer analysis & characterization, 2001, Vol.6 (1-2), p.123-145
issn 1023-666X
1563-5341
language eng
recordid cdi_crossref_primary_10_1080_10236660008034654
source Taylor and Francis Science and Technology Collection
subjects Critical conditions
Liquid chromatography
Polymer/absorbent interactions
title Liquid Chromatography of Polymers at the Exclusion - Adsorption Transition Point: Physicochemical Interpretation
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-08T00%3A25%3A30IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref_infor&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Liquid%20Chromatography%20of%20Polymers%20at%20the%20Exclusion%20-%20Adsorption%20Transition%20Point:%20Physicochemical%20Interpretation&rft.jtitle=International%20journal%20of%20polymer%20analysis%20&%20characterization&rft.au=Baran,%20Katia&rft.date=2001&rft.volume=6&rft.issue=1-2&rft.spage=123&rft.epage=145&rft.pages=123-145&rft.issn=1023-666X&rft.eissn=1563-5341&rft_id=info:doi/10.1080/10236660008034654&rft_dat=%3Ccrossref_infor%3E10_1080_10236660008034654%3C/crossref_infor%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c344t-ae6c0c32b93d02d82dba37eac72bad8017d1b059b51af01a2b03a7a75540f03e3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true