IDENTIFICATION OF THE ISOMERIC TRANSFORMATION PRODUCT FROM 2-(DIMETHYLAMINO)ETHYL-(DIMETHYLPHOSPHORAMIDO)FLUORIDATE

Using 1 H, 13 C, 19 F, 31 P, and 14 N NMR spectroscopy, it has been demonstrated that 2-(dimethylamino)ethyl-dimethylphosphoramidofluoridate undergoes spontaneous isomerization to dimethylaziridinium-dimethylamidofluorophosphate.

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Bibliographic Details
Published in:Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 2004-01, Vol.179 (1), p.49-53
Main Authors: Halamek, Emil, Kobliha, Zbynˆk, Hrabal, Richard
Format: Article
Language:English
Subjects:
Isomeration
NMR identification
organophosphate
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Description
Summary:Using 1 H, 13 C, 19 F, 31 P, and 14 N NMR spectroscopy, it has been demonstrated that 2-(dimethylamino)ethyl-dimethylphosphoramidofluoridate undergoes spontaneous isomerization to dimethylaziridinium-dimethylamidofluorophosphate.
ISSN:1042-6507
1563-5325
DOI:10.1080/10426500490257023