The Molecular Design of "Carcass"-Type Phosphoranes, Based on the Reaction of P(III)-Cyclic Derivatives and Unsaturated Activated Compounds

The methodology for the synthesis of carcass-type (cage-like type) phosphoranes was developed, which allows us to obtain the products of the given structure with a high regio- and stereoselectivity in the result of cascade processes.

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Bibliographic Details
Published in:Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 2011-03, Vol.186 (4), p.652-656
Main Authors: Abdrakhmanova, L. M., Мironov, V. F., Gryaznova, T. P., Katsyuba, S. A., Dimukhametov, M. N.
Format: Article
Language:English
Subjects:
Cascade reaction
chloral
hexafluoroacetone
phosphonate
phosphorane
quantum-chemical calculations
X-ray analysis
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Description
Summary:The methodology for the synthesis of carcass-type (cage-like type) phosphoranes was developed, which allows us to obtain the products of the given structure with a high regio- and stereoselectivity in the result of cascade processes.
ISSN:1042-6507
1563-5325
DOI:10.1080/10426507.2010.521434