Synthesis and Crystal Structures of Zinc(II) Complexes with Schiff Bases Derived from 2-Acetylpyridine

A series of mononuclear zinc(II) complexes, with the formulae [ZnBr(MEA)N 3 ] (1), [Zn(MA)I 2 ] (2), and [ZnCl(PA)N 3 ] (3), where MEA, MA, and PA are N-methyl-N′-(1-pyridin-2-ylethylidene)ethane-1,2-diamine, (2-morpholin-4-ylethyl)-(1-pyridin-2-ylethylidene)amine, and (2-piperidin-1-ylethyl)-(1-pyr...

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Bibliographic Details
Published in:Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry metal-organic, and nano-metal chemistry, 2011-07, Vol.41 (6), p.652-656
Main Author: Han, Li-Lu
Format: Article
Language:English
Subjects:
Crystal structure
Diffraction
Distortion
Nanocomposites
Nanomaterials
Nanostructure
Schiff base
Synthesis
X-rays
zinc(II) complex
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Summary:A series of mononuclear zinc(II) complexes, with the formulae [ZnBr(MEA)N 3 ] (1), [Zn(MA)I 2 ] (2), and [ZnCl(PA)N 3 ] (3), where MEA, MA, and PA are N-methyl-N′-(1-pyridin-2-ylethylidene)ethane-1,2-diamine, (2-morpholin-4-ylethyl)-(1-pyridin-2-ylethylidene)amine, and (2-piperidin-1-ylethyl)-(1-pyridin-2-ylethylidene)amine, respectively, have been synthesized and structurally characterized by elemental analyses, IR, and single crystal X-ray diffraction methods. The Zn atoms in (1) and (2) adopt distorted square pyramidal geometry, and that in (3) adopts geometry between the square pyramidal and the trigonal-bipyramidal.
ISSN:1553-3174
1553-3182
DOI:10.1080/15533174.2011.568456