Alendronic acid bearing acrylic monomer to produce heat resistant polyacrylonitrile copolymer and nanofibers

A new bisphosphonate-bearing acrylic monomer was synthesized with the Aza-Michael addition reaction from sodium alendronate and polyethylene glycol diacrylate. The PAN copolymer of the new monomer and acrylonitrile was heat resistant. In TGA analysis, the char yield of the copolymer at 650°C was hig...

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Bibliographic Details
Published in:Polymer-plastics technology and engineering 2021-11, Vol.60 (17), p.1833-1844
Main Authors: Yılmaz, Mustafa, Süer, N. Ceren, Eren, Tarık, Akar, Ahmet
Format: Article
Language:English
Subjects:
Acid resistance
alendronic acid
Chemical synthesis
Copolymers
Flame-retardance
Michael reaction
Monomers
nanofiber
Nanofibers
poly(ethylene glycol) diacrylate
Polyacrylonitrile
Polyethylene glycol
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Summary:A new bisphosphonate-bearing acrylic monomer was synthesized with the Aza-Michael addition reaction from sodium alendronate and polyethylene glycol diacrylate. The PAN copolymer of the new monomer and acrylonitrile was heat resistant. In TGA analysis, the char yield of the copolymer at 650°C was higher than that of PAN and the commercial poly(acrylonitrile-co-methyl acrylate) while poly(acrylonitrile-co-PEGDA-Ald) copolymers started to decompose at a lower temperature. T g of the copolymers was considerably lower than PAN. Nanofibers were produced successfully by the electrospinning method from the mixture of poly(acrylonitrile-co-PEGDA-Ald) and poly(acrylonitrile-co-methyl acrylate). The poly(acrylonitrile-co-PEGDA-Ald) was also used to extract the copper ion from water.
ISSN:2574-0881
0360-2559
2574-089X
1525-6111
DOI:10.1080/25740881.2021.1934015