Development of biocompatible packaging material: starch/PVA-based bio-composite enhanced with hydroxypropyl methylcellulose

• Published in: Polymer-plastics technology and engineering 2024-11, Vol.63 (17), p.2418-2432
• Main Authors: Kader, Md. Abdul, Shahruzzaman, Md, Parvin, Nehar, Shams, Kashfia, Kamruzzaman, Mohammad, Haque, Papia, Khan, Mubarak A.
• Format: Article
• Language: English
• Subjects: Anaerobic conditions; Biocompatibility; Biofilms; Bonding strength; Chemical analysis; Chemical bonds; Hydrogen bonding; Hydrogen embrittlement; Mechanical properties; Moisture; Packaging; Polymer blends; Polyvinyl alcohol; Soil chemistry; Soil testing; Solubility; Tensile strength; Thermal stability
• ISSN: 2574-0881; 0360-2559; 2574-089X; 1525-6111
• DOI: 10.1080/25740881.2024.2374998

Hydroxypropyl methylcellulose (HPMC) incorporated bio-composite films (unplasticized and plasticized) were prepared from pregelatinized maize starch/polyvinyl alcohol (PMS/PVA) blends by solution casting method. 10% boric acid (BA) was used as crosslinker. The physico-mechanical properties (tensile strength (TS), elongation at break (%EB), water solubility and moisture uptake) of the bio-composite films were studied. The thermo-chemical stability of the biofilms was studied by FT-IR, TGA and DSC analysis. TS, %EB, water solubility and moisture absorbency of 10% HPMC containing unplasticized films were found 38.1 MPa, 8.5%, 61% and 32.3%, respectively, however, the films were hard and brittle. On the contrary, TS, %EB, water solubility and moisture absorbency of 10% HPMC plasticized films were found 19.2 MPa, 28.5%, 62.2% and 57.3%. The biofilms exhibited relatively low water solubility and moisture uptake compared to higher HPMC containing composite. The thermo-chemical analysis revealed that the HPMC incorporated plasticized film was more thermally stable compared to pure PMS, PVA, HPMC and other bio composite films due to strong hydrogen bonding interaction with BA. The biodegradability of HPMC incorporated plasticized films was confirmed by soil burial test (anaerobic condition, RH 98%, 3 months). Therefore, the plasticized biofilm would be considered an alternative approach for biocompatible packaging material.