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Ru(II) Tris(3,8-Dibromo-1,10-Phenanthroline)-A New Versatile Core for the Divergent Synthesis of Hyperbranched Systems

We report the first synthesis of Ru(II) tris(3,8-dibromo-1,10-phenanthroline) bishexafluorophosphate (1), and we demonstrate its utility as a building core for the divergent synthesis of hyperbranched systems by coupling with phenylacetylene in the preparation of Ru(II) tris(3,8-diphenylethynyl-1,10...

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Bibliographic Details
Published in:Synthetic communications 2004, Vol.34 (19), p.3491-3496
Main Authors: Sotiriou-Leventis, Chariklia, Yang, Jinhua, Duan, Penggao, Leventis, Nicholas
Format: Article
Language:English
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Summary:We report the first synthesis of Ru(II) tris(3,8-dibromo-1,10-phenanthroline) bishexafluorophosphate (1), and we demonstrate its utility as a building core for the divergent synthesis of hyperbranched systems by coupling with phenylacetylene in the preparation of Ru(II) tris(3,8-diphenylethynyl-1,10-phenanthroline) dihexafluorophosphate (2).
ISSN:0039-7911
1532-2432
DOI:10.1081/SCC-200030975