Enantioselective Addition of Diethylzinc to Aromatic Aldehydes Catalyzed by New Chiral Oxazolidine Ligand

The chiral oxazolidine ligand can catalyze the enantioselective addition of diethylzinc to aromatic aldehydes at room temperature with high enantioselectivity (98-99% ee). The conditions for this catalytic process are both mild and simple as compared with the same kind catalyst.

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Published in:Synthetic communications 2005-07, Vol.35 (13), p.1819-1823
Main Authors: Kang, Yong-feng, Liu, Lei, Wang, Rui, Ni, Ming, Han, Zhi-jian
Format: Article
Language:English
Subjects:
addition
aldehydes
diethylzinc
enantioselectivity
Oxazolidine
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cited_by cdi_FETCH-LOGICAL-c286t-730259cb613b9f695e83806c40049645450872b421163efc89847384768e61d83
cites cdi_FETCH-LOGICAL-c286t-730259cb613b9f695e83806c40049645450872b421163efc89847384768e61d83
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creator Kang, Yong-feng
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description The chiral oxazolidine ligand can catalyze the enantioselective addition of diethylzinc to aromatic aldehydes at room temperature with high enantioselectivity (98-99% ee). The conditions for this catalytic process are both mild and simple as compared with the same kind catalyst.
doi_str_mv 10.1081/SCC-200063964
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subjects addition
aldehydes
diethylzinc
enantioselectivity
Oxazolidine
title Enantioselective Addition of Diethylzinc to Aromatic Aldehydes Catalyzed by New Chiral Oxazolidine Ligand
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