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SYNTHESIS AND CHARACTERIZATION OF DIORGANOTIN COMPOUNDS CONTAINING SILICON AND GERMANIUM AND CRYSTAL STRUCTURE OF PRECURSOR CARBOXY-ETHYLTRICHLOROGERMANIUM
Eight compounds of general formula [R 1 (CH 3 ) 2 SiCH 2 ] 2 Sn- [O 2 CCH 2 (R 2 )CHGeR 3 3 ] 2 [R 1 = CH 3 , C 2 H 5 ; R 2 = C 6 H 5 , C 6 H 4 OMe-3/4, R 3 = CH 3 , N(CH 2 CH 2 O) 3 ] have been synthesised from [R 1 (CH 3 ) 2 SiCH 2 ] 2 SnCl 2 and R 3 3 GeCH(R 2 )CH 2 CO 2 H in the presence of trie...
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| Published in: | Synthesis and reactivity in inorganic and metal-organic chemistry 2001-02, Vol.31 (2), p.277-295 |
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| Main Authors: | , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c284t-c47dedb91d51688dfc7036c94c20ef5e96b5963461f545bbb476a167270d3cf3 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c284t-c47dedb91d51688dfc7036c94c20ef5e96b5963461f545bbb476a167270d3cf3 |
| container_end_page | 295 |
| container_issue | 2 |
| container_start_page | 277 |
| container_title | Synthesis and reactivity in inorganic and metal-organic chemistry |
| container_volume | 31 |
| creator | Choudhary, M. Aziz Mazhar, M. Salma, U. Ali, S. Qinglan, X. Molloy, K. C. |
| description | Eight compounds of general formula [R
1
(CH
3
)
2
SiCH
2
]
2
Sn- [O
2
CCH
2
(R
2
)CHGeR
3
3
]
2
[R
1
= CH
3
, C
2
H
5
; R
2
= C
6
H
5
, C
6
H
4
OMe-3/4, R
3
= CH
3
, N(CH
2
CH
2
O)
3
] have been synthesised from [R
1
(CH
3
)
2
SiCH
2
]
2
SnCl
2
and R
3
3
GeCH(R
2
)CH
2
CO
2
H in the presence of triethylamine. (Me
3
CCH
2
)
3
SnO
2
CCH
2
(R
1
)CHGe(R
2
)
3
[R
1
= C
6
H
5
, C
6
H
4
OMe-3; R
2
= N(CH
2
CH
2
O)
3
] have been synthesised similarly from (Me
3
CCH
2
)
3
SnCl. The compounds have been characterised by
1
H,
13
C,
29
Si and
119
Sn NMR. The structure of a precursor, Cl
3
GeCH(Ph)CH
2
CO
2
H, has been re-determined and shown to be a hydrogen-bonded dimer rather than a monomer as previously described. |
| doi_str_mv | 10.1081/SIM-100002047 |
| format | article |
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1
(CH
3
)
2
SiCH
2
]
2
Sn- [O
2
CCH
2
(R
2
)CHGeR
3
3
]
2
[R
1
= CH
3
, C
2
H
5
; R
2
= C
6
H
5
, C
6
H
4
OMe-3/4, R
3
= CH
3
, N(CH
2
CH
2
O)
3
] have been synthesised from [R
1
(CH
3
)
2
SiCH
2
]
2
SnCl
2
and R
3
3
GeCH(R
2
)CH
2
CO
2
H in the presence of triethylamine. (Me
3
CCH
2
)
3
SnO
2
CCH
2
(R
1
)CHGe(R
2
)
3
[R
1
= C
6
H
5
, C
6
H
4
OMe-3; R
2
= N(CH
2
CH
2
O)
3
] have been synthesised similarly from (Me
3
CCH
2
)
3
SnCl. The compounds have been characterised by
1
H,
13
C,
29
Si and
119
Sn NMR. The structure of a precursor, Cl
3
GeCH(Ph)CH
2
CO
2
H, has been re-determined and shown to be a hydrogen-bonded dimer rather than a monomer as previously described.</description><identifier>ISSN: 0094-5714</identifier><identifier>EISSN: 1532-2440</identifier><identifier>DOI: 10.1081/SIM-100002047</identifier><language>eng</language><publisher>Taylor & Francis Group</publisher><ispartof>Synthesis and reactivity in inorganic and metal-organic chemistry, 2001-02, Vol.31 (2), p.277-295</ispartof><rights>Copyright Taylor & Francis Group, LLC 2001</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c284t-c47dedb91d51688dfc7036c94c20ef5e96b5963461f545bbb476a167270d3cf3</citedby><cites>FETCH-LOGICAL-c284t-c47dedb91d51688dfc7036c94c20ef5e96b5963461f545bbb476a167270d3cf3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Choudhary, M. Aziz</creatorcontrib><creatorcontrib>Mazhar, M.</creatorcontrib><creatorcontrib>Salma, U.</creatorcontrib><creatorcontrib>Ali, S.</creatorcontrib><creatorcontrib>Qinglan, X.</creatorcontrib><creatorcontrib>Molloy, K. C.</creatorcontrib><title>SYNTHESIS AND CHARACTERIZATION OF DIORGANOTIN COMPOUNDS CONTAINING SILICON AND GERMANIUM AND CRYSTAL STRUCTURE OF PRECURSOR CARBOXY-ETHYLTRICHLOROGERMANIUM</title><title>Synthesis and reactivity in inorganic and metal-organic chemistry</title><description>Eight compounds of general formula [R
1
(CH
3
)
2
SiCH
2
]
2
Sn- [O
2
CCH
2
(R
2
)CHGeR
3
3
]
2
[R
1
= CH
3
, C
2
H
5
; R
2
= C
6
H
5
, C
6
H
4
OMe-3/4, R
3
= CH
3
, N(CH
2
CH
2
O)
3
] have been synthesised from [R
1
(CH
3
)
2
SiCH
2
]
2
SnCl
2
and R
3
3
GeCH(R
2
)CH
2
CO
2
H in the presence of triethylamine. (Me
3
CCH
2
)
3
SnO
2
CCH
2
(R
1
)CHGe(R
2
)
3
[R
1
= C
6
H
5
, C
6
H
4
OMe-3; R
2
= N(CH
2
CH
2
O)
3
] have been synthesised similarly from (Me
3
CCH
2
)
3
SnCl. The compounds have been characterised by
1
H,
13
C,
29
Si and
119
Sn NMR. The structure of a precursor, Cl
3
GeCH(Ph)CH
2
CO
2
H, has been re-determined and shown to be a hydrogen-bonded dimer rather than a monomer as previously described.</description><issn>0094-5714</issn><issn>1532-2440</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><recordid>eNptkMtOwzAQRS0EEqWwZJ8fCNiJ81oaN00sJXZlOxJhE-UpFbUNciqhfgs_S0oRK2Yzc6U7Z3EAeETwCcEQPSuW2wjO40AcXIEF8lzHdjCG12ABYYRtL0D4FtxN0zuEKESuswBfquQ6jRVTFuEri6ZEEqpjyd6IZoJbYm2tmJAJ4UIzblGRb0TBV2q-uCaMM55YimVsjj-AJJY54azILzhZKk0yS2lZUF3I-MzbyJgWUglpUSJfxGtpxzotMy0ZTTMhxR_iHtwM9W7qH373Euh1rGlqZyJhlGR264T4aLc46PquiVDnIT8Mu6ENoOu3EW4d2A9eH_mNF_ku9tHgYa9pGhz4NfIDJ4Cd2w7uEtgXbGvGaTL9UH2Y7b42pwrB6iy2msVWf2Lnfnjpbw_DaPb152h2XXWsT7vRDKY-tNupcv9__QZoKHLk</recordid><startdate>20010228</startdate><enddate>20010228</enddate><creator>Choudhary, M. Aziz</creator><creator>Mazhar, M.</creator><creator>Salma, U.</creator><creator>Ali, S.</creator><creator>Qinglan, X.</creator><creator>Molloy, K. C.</creator><general>Taylor & Francis Group</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20010228</creationdate><title>SYNTHESIS AND CHARACTERIZATION OF DIORGANOTIN COMPOUNDS CONTAINING SILICON AND GERMANIUM AND CRYSTAL STRUCTURE OF PRECURSOR CARBOXY-ETHYLTRICHLOROGERMANIUM</title><author>Choudhary, M. Aziz ; Mazhar, M. ; Salma, U. ; Ali, S. ; Qinglan, X. ; Molloy, K. C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c284t-c47dedb91d51688dfc7036c94c20ef5e96b5963461f545bbb476a167270d3cf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2001</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Choudhary, M. Aziz</creatorcontrib><creatorcontrib>Mazhar, M.</creatorcontrib><creatorcontrib>Salma, U.</creatorcontrib><creatorcontrib>Ali, S.</creatorcontrib><creatorcontrib>Qinglan, X.</creatorcontrib><creatorcontrib>Molloy, K. C.</creatorcontrib><collection>CrossRef</collection><jtitle>Synthesis and reactivity in inorganic and metal-organic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Choudhary, M. Aziz</au><au>Mazhar, M.</au><au>Salma, U.</au><au>Ali, S.</au><au>Qinglan, X.</au><au>Molloy, K. C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>SYNTHESIS AND CHARACTERIZATION OF DIORGANOTIN COMPOUNDS CONTAINING SILICON AND GERMANIUM AND CRYSTAL STRUCTURE OF PRECURSOR CARBOXY-ETHYLTRICHLOROGERMANIUM</atitle><jtitle>Synthesis and reactivity in inorganic and metal-organic chemistry</jtitle><date>2001-02-28</date><risdate>2001</risdate><volume>31</volume><issue>2</issue><spage>277</spage><epage>295</epage><pages>277-295</pages><issn>0094-5714</issn><eissn>1532-2440</eissn><abstract>Eight compounds of general formula [R
1
(CH
3
)
2
SiCH
2
]
2
Sn- [O
2
CCH
2
(R
2
)CHGeR
3
3
]
2
[R
1
= CH
3
, C
2
H
5
; R
2
= C
6
H
5
, C
6
H
4
OMe-3/4, R
3
= CH
3
, N(CH
2
CH
2
O)
3
] have been synthesised from [R
1
(CH
3
)
2
SiCH
2
]
2
SnCl
2
and R
3
3
GeCH(R
2
)CH
2
CO
2
H in the presence of triethylamine. (Me
3
CCH
2
)
3
SnO
2
CCH
2
(R
1
)CHGe(R
2
)
3
[R
1
= C
6
H
5
, C
6
H
4
OMe-3; R
2
= N(CH
2
CH
2
O)
3
] have been synthesised similarly from (Me
3
CCH
2
)
3
SnCl. The compounds have been characterised by
1
H,
13
C,
29
Si and
119
Sn NMR. The structure of a precursor, Cl
3
GeCH(Ph)CH
2
CO
2
H, has been re-determined and shown to be a hydrogen-bonded dimer rather than a monomer as previously described.</abstract><pub>Taylor & Francis Group</pub><doi>10.1081/SIM-100002047</doi><tpages>19</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0094-5714 |
| ispartof | Synthesis and reactivity in inorganic and metal-organic chemistry, 2001-02, Vol.31 (2), p.277-295 |
| issn | 0094-5714 1532-2440 |
| language | eng |
| recordid | cdi_crossref_primary_10_1081_SIM_100002047 |
| source | Taylor and Francis:Jisc Collections:Taylor and Francis Read and Publish Agreement 2024-2025:Science and Technology Collection (Reading list) |
| title | SYNTHESIS AND CHARACTERIZATION OF DIORGANOTIN COMPOUNDS CONTAINING SILICON AND GERMANIUM AND CRYSTAL STRUCTURE OF PRECURSOR CARBOXY-ETHYLTRICHLOROGERMANIUM |
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