Mean absorption coefficient of H 2 O–air–MgCl 2 /CaCl 2 /NaCl thermal plasmas

• Published in: Journal of physics. D, Applied physics Applied physics, 2012-12, Vol.45 (48), p.485206
• Main Authors: Hannachi, R, Cressault, Y, Salem, D, Teulet, Ph, Béji, L, Lakhdar, Z Ben
• Format: Article
• Language: English
• ISSN: 0022-3727; 1361-6463
• DOI: 10.1088/0022-3727/45/48/485206

Under the local thermodynamic equilibrium hypothesis, the mean absorption coefficients (MACs) were calculated for H 2 O–air–MgCl 2 /CaCl 2 /NaCl thermal plasmas in a temperature range from 300 to 30 000 K and at atmospheric pressure. The MACs were computed under the hypothesis of isothermal plasmas which allows a good description of the radiation absorbed in cold regions. In this study, we took into account the absorption radiation resulting from the atomic continuum, molecular continuum, atomic lines and some molecular bands. Free–free transitions (bremsstrahlung) and free–bound (electron–ion recombination and electron attachment) or bound–free transitions in terms of absorption were considered for the calculation of atomic continuum. For bound–bound transitions, natural, resonance, van der Waals, Stark and Doppler effects were taken into account for the line broadenings while the escape factors were used to treat the self-absorption of the resonance lines. Molecular continuum was considered for the main molecules (H 2 , O 2 , N 2 , OH, NO, H 2 O, N 2 O, NO 2 , O 3 , NO 3 and N 2 O 5 ) whereas we studied only diatomic systems O 2 , N 2 , NO and for the absorption of molecular bands. The influence of the proportion of MgCl 2 , CaCl 2 or NaCl in a water–air mixture was analysed as the effect of the strong self-absorbed resonance lines of the alkaline salts (Ca, Ca + , Na, Na + , Mg, Mg + , Cl and Cl + ). Our results show that a low concentration of alkaline salts (less than 1% in molar proportions) in the plasma increased the MACs at low temperatures ( T