Anisotropic hybridization probed by polarization dependent x-ray absorption spectroscopy in VI 3 van der Waals Mott ferromagnet

• Published in: Journal of physics. Condensed matter 2023-10, Vol.35 (40), p.405601
• Main Authors: Sant, R, De Vita, A, Polewczyk, V, Pierantozzi, G M, Mazzola, F, Vinai, G, van der Laan, G, Panaccione, G, Brookes, N B
• Format: Article
• Language: English
• ISSN: 0953-8984; 1361-648X
• DOI: 10.1088/1361-648X/ace1bf

Polarization dependent x-ray absorption spectroscopy was used to study the magnetic ground state and the orbital occupation in bulk-phase VI van der Waals crystals below and above the ferromagnetic and structural transitions. X-ray natural linear dichroism and x-ray magnetic circular dichroism spectra acquired at the VL2,3edges are compared against multiplet cluster calculations within the frame of the ligand field theory to quantify the intra-atomic electronic interactions at play and evaluate the effects of symmetry reduction occurring in a trigonally distorted VI unit. We observed a non zero linear dichroism proving the presence of an anisotropic charge density distribution around the V ion due to the unbalanced hybridization between the vanadium and the ligand states. Such hybridization acts as an effective trigonal crystal field, slightly lifting the degeneracy of thet2g2ground state. However, the energy splitting associated to the distortion underestimates the experimental band gap, suggesting that the insulating ground state is stabilized by Mott correlation effects rather than via a Jahn-Teller mechanism. Our results clarify the role of the distortion in VI and establish a benchmark for the study of the spectroscopic properties of other van der Waals halides, including emerging 2D materials with mono and few-layers thickness, whose fundamental properties might be altered by reduced dimensions and interface proximity.