Loading…

Davydov Splitting, Resonance Effect and Phonon Dynamics in Chemical Vapor Deposition Grown Layered MoS 2

We present comprehensive temperature dependent Raman measurements for chemical vapor deposition grown horizontally aligned layered MoS in a temperature range of 4-330 K under a resonance condition. Our analysis of temperature dependent phonon frequency shift and linewidth suggests a finite role of t...

Full description

Saved in:
Bibliographic Details
Published in:Nanotechnology 2021-07, Vol.32 (28), p.285705
Main Authors: Kumar, Deepu, Singh, Birender, Kumar, Rahul, Kumar, Mahesh, Kumar, Pradeep
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:We present comprehensive temperature dependent Raman measurements for chemical vapor deposition grown horizontally aligned layered MoS in a temperature range of 4-330 K under a resonance condition. Our analysis of temperature dependent phonon frequency shift and linewidth suggests a finite role of three and four phonon anharmonic effect. We observe Davydov splitting of the out-of-plane ( ) and in-plane (E2g1) modes for both three layer (3L) and few layer (FL) systems. The number of Davydov splitting components are found more in FL compared to 3L MoS , which suggests that it increases with an increasing number of layers. Further, Davydov splitting is analyzed as a function of temperature. Temperature evaluation of the Raman spectra shows that the Davydov splitting, especially for mode, is very strong and well resolved at low temperature. We observe that mode shows the splitting at low temperature, whileE2g1mode is split even at room temperature, which suggests a prominent role of mode in the interlayer interaction at low temperature. Further, an almost 60-fold increase in the intensity of the phonon modes at low temperature clearly shows the temperature dependent tuning of the resonance effect.
ISSN:0957-4484
1361-6528
DOI:10.1088/1361-6528/abf37b