Transition metals in the process of complexation with organic ligands containing heteroatoms in the structure

The synthesis and research of copper subgroup metal complexes with organic ligands, which have several heteroatoms in their structure, is highly perceptive. Since the resulting complex compounds differ in physical and chemical properties from the original organic compounds they will have a set of ne...

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Bibliographic Details
Published in:Journal of physics. Conference series 2021-08, Vol.1989 (1), p.12027
Main Authors: Marakina, E I, Andrienko, O S, Sachkov, V I, Medvedev, R, Amelichkin, I, Shcherbakov, P S
Format: Article
Language:English
Subjects:
Ammonia
Chemical properties
Complex compounds
Coordination compounds
Copper
Ligands
Organic compounds
Reagents
Subgroups
Transition metals
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Summary:The synthesis and research of copper subgroup metal complexes with organic ligands, which have several heteroatoms in their structure, is highly perceptive. Since the resulting complex compounds differ in physical and chemical properties from the original organic compounds they will have a set of new characteristics of practical significance. In this study, 2-mercaptonicotinic acid and 2-mercapto-4(3H)-quinazolinone were used. During the research, complex compounds of metals of the copper subgroup were obtained from aqueous and water-alcohol solutions. The resulting compounds represent colored powder-like materials. The coordination of the organic reagent to metal ions was established by instrumental methods of analysis. The effect of the introduced reagent (alkali, ammonia) on the coordination of the organic reagent was investigated.
ISSN:1742-6588
1742-6596
DOI:10.1088/1742-6596/1989/1/012027