Force-induced desorption of copolymeric comb polymers

We investigate a lattice model of comb copolymers that can adsorb at a surface and that are subject to a force causing desorption. The teeth (the comb’s side chains) and the backbone of the comb are chemically distinct and can interact differently with the surface. That is, the strength of the surfa...

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Bibliographic Details
Published in:Journal of physics. A, Mathematical and theoretical Mathematical and theoretical, 2024-03, Vol.57 (13), p.135001
Main Authors: Janse van Rensburg, E J, Soteros, C E, Whittington, S G
Format: Article
Language:English
Subjects:
copolymer combs
phase diagram
self-avoiding walk
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Summary:We investigate a lattice model of comb copolymers that can adsorb at a surface and that are subject to a force causing desorption. The teeth (the comb’s side chains) and the backbone of the comb are chemically distinct and can interact differently with the surface. That is, the strength of the surface interaction can be different for the monomers in the teeth and in the backbone. We consider several cases including (i) the uniform case where the number of teeth is fixed and the lengths of the branches in the backbone and the lengths of the teeth are all identical, (ii) the case where the teeth are short compared to the branches in the backbone, (iii) the situation where the teeth are long compared to the backbone, and (iv) the case where the number of teeth approaches infinity. We obtain expressions for the free energies in the thermodynamic limit in terms of those for self-avoiding walks and discuss the nature of the phase diagrams of the model.
ISSN:1751-8113
1751-8121
DOI:10.1088/1751-8121/ad27a0