Performance analysis of A 3 B 2 X 9 (Cs 3 Bi 2 I 9 ) based perovskite photovoltaic tandem structure with crystalline Silicon (c-Si)

• Published in: IOP conference series. Materials Science and Engineering 2024-04, Vol.1300 (1), p.12005
• Main Authors: Goutham Kumar, Shreyus, Surya Teja Reddy, Tadi, Suraj, N, Prashanth, C R, Honnavar, Gajanan V
• Format: Article
• Language: English
• ISSN: 1757-8981; 1757-899X
• DOI: 10.1088/1757-899X/1300/1/012005

The efficiency of solar cells with single-junction utilizing organic-inorganic hybrid perovskites have attained a value more than 25.5%. The device power conversion efficiency (PCE) can be improved further either by optimizing the absorber layer (Perovskite film) or by investigating the novel device structures such as tandem based solar cells with perovskite and silicon. This combination of top cell (Perovskite solar cell) and bottom cell (Silicon solar cell) can improve the PCE which surpasses the Shockley-Queisser limit of single-junction solar cells by utilizing a wider range of solar spectrum. This paper presents an optimization and simulation of standalone Cs 3 Bi 2 I 9 perovskite solar cell which was later integrated with a c-Si solar cell to simulate a tandem structure using SCAPS-1D software. The aim is to investigate the performance enhancement of the perovskite solar cell by optimizing it and stacking it on top of a high-efficiency c-Si solar cell using a four-terminal (4T) structure. At a short-circuit current density of 16.165 mA/cm 2 and an open-circuit voltage of 1.41 V, the simulation findings demonstrate that the Cs 3 Bi 2 I 9 perovskite solar cell exhibits a high-power conversion efficiency of 20.37%. The tandem structure demonstrates an enhanced power conversion efficiency of 31.59% which is significantly higher than the efficiency of the individual cells. The Cs 3 Bi 2 I 9 perovskite solar cell is a great choice for application in tandem systems with c-Si solar cells for high-efficiency, according to the simulation results. This study provides valuable insights for the development of efficient perovskite/c-Si tandem solar cells.