Multiresidue determination of pesticides in drinking and related waters by gas chromatography/mass spectrometry after solid-phase extraction : Interlaboratory study

• Published in: Journal of AOAC International 2001-09, Vol.84 (5), p.1420-1429
• Main Authors: VAN HOOF, Francois, VAN WIELE, Peter, BRUCHET, Auguste, SCHMITZ, Isabelle, BOBELDIJI, Ivana, SACHER, Frank, VENTURA, Francesc, MARTI, Isabel, MARECOS DO MONTE, Maria Helena, SA DA COSTA, Margarida
• Format: Article
• Language: English
• Subjects: Algorithms; Biological and medical sciences; Food industries; Food toxicology; Fundamental and applied biological sciences. Psychology; Gas Chromatography-Mass Spectrometry; Indicators and Reagents; Non alcoholic beverage industries and mineral waters; Pesticide Residues - analysis; Reference Standards; Reproducibility of Results; Solutions; Solvents; Water Pollutants, Chemical - analysis; Water Supply - analysis
• ISSN: 1060-3271; 1944-7922
• DOI: 10.1093/jaoac/84.5.1420

As part of a project funded by the European Commission (EC) for the development and evaluation of multiresidue methods for analysis of drinking and related waters, 15 European laboratories evaluated a method using styrene-divinylbenzene co-polymer solid-phase extraction followed by gas chromatography/mass spectrometry. The main aim of the study was to evaluate whether the method meets the requirements of EC Directive 98/83 in terms of accuracy, precision, and detection limit for 22 pesticides according to the following requirements: limit of detection, < or = 0.025 microg/L; accuracy, expressed as recovery between 75 and 125%; and precision, expressed as repeatability relative standard deviation of the method of < 12.5% and as reproducibility relative standard deviation of the method of < 25%. Analyses for unknown concentrations were performed with fortified commercial bottled and tap waters. All laboratories were able to achieve detection limits of 0.01 microg/L for all pesticides except dimethoate and desisopropylatrazine (0.02 microg/L). The criteria for repeatability were met for all compounds except trifluralin, dimethoate, and lindane in bottled water and chlorpyrifos, dimethoate, and lindane in tap water. The criteria for reproducibility were met for all compounds except trifluralin, dimethoate, and lindane in bottled water and pendimethalin, chlorpyrifos, dimethoate, terbutryn, and lindane in tap water. In terms of accuracy, the method meets the requirements for all pesticides in both matrixes, except for lindane in bottled water and lindane and chlorpyrifos in tap water.