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Optically Stimulated Luminescence Materials Based on CaS for Gamma and Fast Neutron Dosimetry

The OSL selective dosimetric materials based on CaS doped with Bi and In ions were synthesised. Physicochemical properties of such materials are analysed in detail and a model of traps and recombination centres is proposed. For CaS-In phosphors the emission in the range of 2.4-2.1 eV is assigned to...

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Bibliographic Details
Published in:Radiation protection dosimetry 1996-06, Vol.65 (1-4), p.297-300
Main Authors: Hütt, G., Jaek, I.
Format: Article
Language:English
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Summary:The OSL selective dosimetric materials based on CaS doped with Bi and In ions were synthesised. Physicochemical properties of such materials are analysed in detail and a model of traps and recombination centres is proposed. For CaS-In phosphors the emission in the range of 2.4-2.1 eV is assigned to the defect Me3+Me+ or Me3+M-, whereas for CaS-Bi phosphors the centres Bi3+ or Bi3+Na+ are responsible for the emission at 2.7 eV. The traps revealed in OSL are attributed to intrinsic defects of CaS (energy level of 1.65 eV) and to a single Me3+ state (1.35-1.45 eV). The a/? ratio of 2000 (arb. units) is reached for the best OSL CaS-In samples synthesised. However, the presence of fading for elaborated OSL dosimetric materials needs further improvement in technology.
ISSN:0144-8420
1742-3406
DOI:10.1093/oxfordjournals.rpd.a031645