Crystal architectures of organic molecular-based magnets

The crystal architectures of molecular materials play deciding roles when it comes to the determination of magnetic properties. In turn, the build-up of these arrangements is shown to depend on the molecular features present in the compounds employed. An analysis of the molecular and supramolecular...

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Bibliographic Details
Published in:Philosophical transactions of the Royal Society of London. Series A: Mathematical, physical, and engineering sciences physical, and engineering sciences, 1999-11, Vol.357 (1762), p.2873-2891
Main Authors: Amabilino, David B., Cirujeda, Joan, Veciana, Jaume
Format: Article
Language:English
Subjects:
Amino radical
Architecture
Atomic interactions
Atoms
Crystals
Hydrogen Bonds
Magnetic Interactions
Magnets
McConnell I
Molecular interactions
Molecules
Organic Magnets
Phenyls
Structure-Magnetism Correlation
Supramolecular Chemsitry
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Summary:The crystal architectures of molecular materials play deciding roles when it comes to the determination of magnetic properties. In turn, the build-up of these arrangements is shown to depend on the molecular features present in the compounds employed. An analysis of the molecular and supramolecular aspects of the α-nitronyl aminoxyl radicals is presented, and a critical appraisal of the state of the art in interpretation of magnetic interactions and ability to crystallize predetermined relative orientations between radicals is presented.
ISSN:1364-503X
1471-2962
DOI:10.1098/rsta.1999.0472