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A new ternary compound with the BGa 8 Ir 4 structure type in the Al–Au–Ir system

Following the recent determination of the Al 3 AuIr structure, a new ternary phase has been identified in the Al–Au–Ir phase diagram. It has a chemical composition Al 9 (Au;Ir) 4 with an apparently low gold content. Its crystal structure has been determined with single-crystal X-ray diffraction. The...

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Bibliographic Details
Published in:Acta crystallographica Section B, Structural science, crystal engineering and materials Structural science, crystal engineering and materials, 2019-02, Vol.75 (1), p.49-52
Main Authors: Kadok, Joris, de Weerd, Marie-Cécile, Boulet, Pascal, Fournée, Vincent, Ledieu, Julian
Format: Article
Language:English
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Summary:Following the recent determination of the Al 3 AuIr structure, a new ternary phase has been identified in the Al–Au–Ir phase diagram. It has a chemical composition Al 9 (Au;Ir) 4 with an apparently low gold content. Its crystal structure has been determined with single-crystal X-ray diffraction. The new compound crystallizes in the tetragonal crystal system and has been successfully solved in space group I 4 1 / acd (Pearson symbol tI 104) with lattice parameters a = 8.6339 (2) and c = 21.8874 (7) Å. Atomic environments are described as well as similarities with the BGa 8 Ir 4 compound.
ISSN:2052-5206
2052-5206
DOI:10.1107/S2052520618016712