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Crystal structure of (aceto-nitrile-κ N )iodido-(2-(naphthalen-1-yl)-6-{1-[(2,4,6-tri-methyl-phen-yl)imino]ethyl}-pyridine-κ 2 N , N ')copper(I)

In the mononuclear title complex, [CuI(C H N)(C H N )], the Cu ion has a distorted tetra-hedral coordination environment, defined by two N atoms of the chelating 2-(naphthalen-1-yl)-6-[(2,4,6-tri-methyl-phen-yl)imino]-pyridine ligand, one N atom of an aceto-nitrile ligand and one iodide ligand. With...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2016-12, Vol.72 (Pt 12), p.1845-1847
Main Authors: Al-Najjar, Nada, Solan, Gregory A, Singh, Kuldip
Format: Article
Language:English
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Summary:In the mononuclear title complex, [CuI(C H N)(C H N )], the Cu ion has a distorted tetra-hedral coordination environment, defined by two N atoms of the chelating 2-(naphthalen-1-yl)-6-[(2,4,6-tri-methyl-phen-yl)imino]-pyridine ligand, one N atom of an aceto-nitrile ligand and one iodide ligand. Within the complex, there are weak intra-molecular C-H⋯N hydrogen bonds, while weak inter-molecular C-H⋯I inter-actions between complex mol-ecules, help to facilitate a three-dimensional network.
ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989016018685