catena -Poly[[bis(1 H -indole-5-carboxylato-κ 2 O , O ′)zinc(II)]-μ-4,4′-azobipyridine-κ 2 N 1 : N 1′ ]

The asymmetric unit of the title coordination polymer [Zn(C 9 H 6 NO 2 ) 2 (C 10 H 8 N 4 )] n , consists of one Zn II cation, one bidentate 1 H -indole-5-carboxylate (I5C) anion and half of a 4,4′-azobipyridine (Abpy) neutral ligand. In the coordination polyhedron, the Zn II ion adopts a distorted o...

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Bibliographic Details
Published in:IUCrData 2021-05, Vol.6 (5), Article x210522
Main Authors: Sathya, Udhayasuriyan, Nirmal Ram, Jeyaraman Selvaraj, Gomathi, Sundaramoorthy, Jegan Jennifer, Samson, Abdul Razak, Ibrahim
Format: Article
Language:English
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Summary:The asymmetric unit of the title coordination polymer [Zn(C 9 H 6 NO 2 ) 2 (C 10 H 8 N 4 )] n , consists of one Zn II cation, one bidentate 1 H -indole-5-carboxylate (I5C) anion and half of a 4,4′-azobipyridine (Abpy) neutral ligand. In the coordination polyhedron, the Zn II ion adopts a distorted octahedral geometry. The coordination polymer is stabilized by a combination of N—H...O and C—H...π interactions, which leads to the formation of wave-like two-dimensional coordination polymeric layers.
ISSN:2414-3146
2414-3146
DOI:10.1107/S2414314621005228