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Selected Phase Equilibria Studies in the Al 2 O 3 –CaO–SiO 2 System
The Al 2 O 3 –CaO–SiO 2 system provides the basis for describing many important chemical processes. Although the system has previously been extensively studied, recent advances in experimental technique have provided the opportunity to obtain accurate liquidus measurements in the low‐silica region a...
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| Published in: | Journal of the American Ceramic Society 2016-02, Vol.99 (2), p.691-704 |
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| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c761-7c8309f2631861acfe75f4b91ae2e481f8f26f45931166935ed8c3d764875d7e3 |
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| cites | cdi_FETCH-LOGICAL-c761-7c8309f2631861acfe75f4b91ae2e481f8f26f45931166935ed8c3d764875d7e3 |
| container_end_page | 704 |
| container_issue | 2 |
| container_start_page | 691 |
| container_title | Journal of the American Ceramic Society |
| container_volume | 99 |
| creator | Haccuria, Elien Crivits, Tijl Hayes, Peter C. Jak, Evgueni |
| description | The Al
2
O
3
–CaO–SiO
2
system provides the basis for describing many important chemical processes. Although the system has previously been extensively studied, recent advances in experimental technique have provided the opportunity to obtain accurate liquidus measurements in the low‐silica region at fixed temperatures. The experimental procedures involve equilibration of high‐purity oxide powder mixtures at selected temperatures, rapid quenching, and accurate measurement of phase compositions using electron probe X‐ray microanalysis. The liquidus isotherms have been determined at selected temperatures between 1503 and 1873 K in the anorthite, gehlenite, pseudowollastonite, corundum, CaAl
12
O
19
, CaAl
2
O
6
, lime, Ca
3
SiO
3
, and Ca
2
SiO
4
primary phase fields. The results are compared with currently available thermodynamic model predictions of the phase chemistry. |
| doi_str_mv | 10.1111/jace.13991 |
| format | article |
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2
O
3
–CaO–SiO
2
system provides the basis for describing many important chemical processes. Although the system has previously been extensively studied, recent advances in experimental technique have provided the opportunity to obtain accurate liquidus measurements in the low‐silica region at fixed temperatures. The experimental procedures involve equilibration of high‐purity oxide powder mixtures at selected temperatures, rapid quenching, and accurate measurement of phase compositions using electron probe X‐ray microanalysis. The liquidus isotherms have been determined at selected temperatures between 1503 and 1873 K in the anorthite, gehlenite, pseudowollastonite, corundum, CaAl
12
O
19
, CaAl
2
O
6
, lime, Ca
3
SiO
3
, and Ca
2
SiO
4
primary phase fields. The results are compared with currently available thermodynamic model predictions of the phase chemistry.</description><identifier>ISSN: 0002-7820</identifier><identifier>EISSN: 1551-2916</identifier><identifier>DOI: 10.1111/jace.13991</identifier><language>eng</language><ispartof>Journal of the American Ceramic Society, 2016-02, Vol.99 (2), p.691-704</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c761-7c8309f2631861acfe75f4b91ae2e481f8f26f45931166935ed8c3d764875d7e3</citedby><cites>FETCH-LOGICAL-c761-7c8309f2631861acfe75f4b91ae2e481f8f26f45931166935ed8c3d764875d7e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27906,27907</link.rule.ids></links><search><contributor>Biernacki, J.</contributor><creatorcontrib>Haccuria, Elien</creatorcontrib><creatorcontrib>Crivits, Tijl</creatorcontrib><creatorcontrib>Hayes, Peter C.</creatorcontrib><creatorcontrib>Jak, Evgueni</creatorcontrib><title>Selected Phase Equilibria Studies in the Al 2 O 3 –CaO–SiO 2 System</title><title>Journal of the American Ceramic Society</title><description>The Al
2
O
3
–CaO–SiO
2
system provides the basis for describing many important chemical processes. Although the system has previously been extensively studied, recent advances in experimental technique have provided the opportunity to obtain accurate liquidus measurements in the low‐silica region at fixed temperatures. The experimental procedures involve equilibration of high‐purity oxide powder mixtures at selected temperatures, rapid quenching, and accurate measurement of phase compositions using electron probe X‐ray microanalysis. The liquidus isotherms have been determined at selected temperatures between 1503 and 1873 K in the anorthite, gehlenite, pseudowollastonite, corundum, CaAl
12
O
19
, CaAl
2
O
6
, lime, Ca
3
SiO
3
, and Ca
2
SiO
4
primary phase fields. The results are compared with currently available thermodynamic model predictions of the phase chemistry.</description><issn>0002-7820</issn><issn>1551-2916</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNotkM1qwzAQhEVpoG7SS59A54JTrWT9HYNJk0LABeduFHlFFJz-WM4ht75D37BPUqftHGaYWdjDR8g9sDmMejw4j3MQ1sIVyUBKyLkFdU0yxhjPteHshtymdBgrWFNkZFVjh37Alr7sXUK6_DjFLu766Gg9nNqIicZXOuyRLjrKaUUF_f78Kl01eh2rcarPacDjjEyC6xLe_eeUbJ-W23Kdb6rVc7nY5F4ryLU3gtnAlQCjwPmAWoZiZ8Ehx8JAMOMtFNIKAKWskNgaL1qtCqNlq1FMycPfW9-_pdRjaN77eHT9uQHWXAg0FwLNLwHxA4UCTV4</recordid><startdate>201602</startdate><enddate>201602</enddate><creator>Haccuria, Elien</creator><creator>Crivits, Tijl</creator><creator>Hayes, Peter C.</creator><creator>Jak, Evgueni</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>201602</creationdate><title>Selected Phase Equilibria Studies in the Al 2 O 3 –CaO–SiO 2 System</title><author>Haccuria, Elien ; Crivits, Tijl ; Hayes, Peter C. ; Jak, Evgueni</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c761-7c8309f2631861acfe75f4b91ae2e481f8f26f45931166935ed8c3d764875d7e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Haccuria, Elien</creatorcontrib><creatorcontrib>Crivits, Tijl</creatorcontrib><creatorcontrib>Hayes, Peter C.</creatorcontrib><creatorcontrib>Jak, Evgueni</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of the American Ceramic Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Haccuria, Elien</au><au>Crivits, Tijl</au><au>Hayes, Peter C.</au><au>Jak, Evgueni</au><au>Biernacki, J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Selected Phase Equilibria Studies in the Al 2 O 3 –CaO–SiO 2 System</atitle><jtitle>Journal of the American Ceramic Society</jtitle><date>2016-02</date><risdate>2016</risdate><volume>99</volume><issue>2</issue><spage>691</spage><epage>704</epage><pages>691-704</pages><issn>0002-7820</issn><eissn>1551-2916</eissn><abstract>The Al
2
O
3
–CaO–SiO
2
system provides the basis for describing many important chemical processes. Although the system has previously been extensively studied, recent advances in experimental technique have provided the opportunity to obtain accurate liquidus measurements in the low‐silica region at fixed temperatures. The experimental procedures involve equilibration of high‐purity oxide powder mixtures at selected temperatures, rapid quenching, and accurate measurement of phase compositions using electron probe X‐ray microanalysis. The liquidus isotherms have been determined at selected temperatures between 1503 and 1873 K in the anorthite, gehlenite, pseudowollastonite, corundum, CaAl
12
O
19
, CaAl
2
O
6
, lime, Ca
3
SiO
3
, and Ca
2
SiO
4
primary phase fields. The results are compared with currently available thermodynamic model predictions of the phase chemistry.</abstract><doi>10.1111/jace.13991</doi><tpages>14</tpages></addata></record> |
| fulltext | fulltext |
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| ispartof | Journal of the American Ceramic Society, 2016-02, Vol.99 (2), p.691-704 |
| issn | 0002-7820 1551-2916 |
| language | eng |
| recordid | cdi_crossref_primary_10_1111_jace_13991 |
| source | Wiley-Blackwell Read & Publish Collection |
| title | Selected Phase Equilibria Studies in the Al 2 O 3 –CaO–SiO 2 System |
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