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Fluorite‐like Li x Ln 5– x Mo 3 O 16.5–1.5 x F x (Ln = La, Pr, Nd) compounds isostructural with Nd 5 Mo 3 O 16
Li x Ln 5– x Mo 3 O 16.5–1.5 x F x (0.8 ≤ x ≤ 1.4 (Ln = La), 0.4 ≤ x ≤ 1 (Ln = Pr), 0.6 ≤ x ≤ 1 (Ln = Nd)) solid solutions on the Ln 5 Mo 3 O 16 –LiLn 4 Mo 3 O 15 F joins of the Ln 2 O 3 –MoO 3 –LiF ternary systems, similar to the fluorite‐related cubic compound Nd 5 Mo 3 O 16 , have been prep...
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| Published in: | Journal of the American Ceramic Society 2020-11, Vol.103 (11), p.6414-6423 |
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| Main Authors: | , , , , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c764-5a903a867764080e7540df02939ddf75af4ebf863a528cbc008ee19506a9a2773 |
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| cites | cdi_FETCH-LOGICAL-c764-5a903a867764080e7540df02939ddf75af4ebf863a528cbc008ee19506a9a2773 |
| container_end_page | 6423 |
| container_issue | 11 |
| container_start_page | 6414 |
| container_title | Journal of the American Ceramic Society |
| container_volume | 103 |
| creator | Voronkova, Valentina Kharitonova, Elena Orlova, Ekaterina Baldin, Egor Gorshkov, Nikolay Goffman, Vladimir Chernyak, Sergei |
| description | Li
x
Ln
5–
x
Mo
3
O
16.5–1.5
x
F
x
(0.8 ≤
x
≤ 1.4 (Ln = La), 0.4 ≤
x
≤ 1 (Ln = Pr), 0.6 ≤
x
≤ 1 (Ln = Nd)) solid solutions on the Ln
5
Mo
3
O
16
–LiLn
4
Mo
3
O
15
F joins of the Ln
2
O
3
–MoO
3
–LiF ternary systems, similar to the fluorite‐related cubic compound Nd
5
Mo
3
O
16
, have been prepared by solid‐state reactions. Substitutions of lithium on the rare‐earth site and fluorine on the oxygen site have been shown to lead to a reversible phase transition accompanied by an anomaly in permittivity and a jump in conductivity by one and half orders of magnitude. In a wet atmosphere, the Li
x
Ln
5–
x
Mo
3
O
16.5–1.5
x
F
x
compounds may have proton conductivity. |
| doi_str_mv | 10.1111/jace.17374 |
| format | article |
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x
Ln
5–
x
Mo
3
O
16.5–1.5
x
F
x
(0.8 ≤
x
≤ 1.4 (Ln = La), 0.4 ≤
x
≤ 1 (Ln = Pr), 0.6 ≤
x
≤ 1 (Ln = Nd)) solid solutions on the Ln
5
Mo
3
O
16
–LiLn
4
Mo
3
O
15
F joins of the Ln
2
O
3
–MoO
3
–LiF ternary systems, similar to the fluorite‐related cubic compound Nd
5
Mo
3
O
16
, have been prepared by solid‐state reactions. Substitutions of lithium on the rare‐earth site and fluorine on the oxygen site have been shown to lead to a reversible phase transition accompanied by an anomaly in permittivity and a jump in conductivity by one and half orders of magnitude. In a wet atmosphere, the Li
x
Ln
5–
x
Mo
3
O
16.5–1.5
x
F
x
compounds may have proton conductivity.</description><identifier>ISSN: 0002-7820</identifier><identifier>EISSN: 1551-2916</identifier><identifier>DOI: 10.1111/jace.17374</identifier><language>eng</language><ispartof>Journal of the American Ceramic Society, 2020-11, Vol.103 (11), p.6414-6423</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c764-5a903a867764080e7540df02939ddf75af4ebf863a528cbc008ee19506a9a2773</citedby><cites>FETCH-LOGICAL-c764-5a903a867764080e7540df02939ddf75af4ebf863a528cbc008ee19506a9a2773</cites><orcidid>0000-0003-3248-3257 ; 0000-0003-3754-7862</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Voronkova, Valentina</creatorcontrib><creatorcontrib>Kharitonova, Elena</creatorcontrib><creatorcontrib>Orlova, Ekaterina</creatorcontrib><creatorcontrib>Baldin, Egor</creatorcontrib><creatorcontrib>Gorshkov, Nikolay</creatorcontrib><creatorcontrib>Goffman, Vladimir</creatorcontrib><creatorcontrib>Chernyak, Sergei</creatorcontrib><title>Fluorite‐like Li x Ln 5– x Mo 3 O 16.5–1.5 x F x (Ln = La, Pr, Nd) compounds isostructural with Nd 5 Mo 3 O 16</title><title>Journal of the American Ceramic Society</title><description>Li
x
Ln
5–
x
Mo
3
O
16.5–1.5
x
F
x
(0.8 ≤
x
≤ 1.4 (Ln = La), 0.4 ≤
x
≤ 1 (Ln = Pr), 0.6 ≤
x
≤ 1 (Ln = Nd)) solid solutions on the Ln
5
Mo
3
O
16
–LiLn
4
Mo
3
O
15
F joins of the Ln
2
O
3
–MoO
3
–LiF ternary systems, similar to the fluorite‐related cubic compound Nd
5
Mo
3
O
16
, have been prepared by solid‐state reactions. Substitutions of lithium on the rare‐earth site and fluorine on the oxygen site have been shown to lead to a reversible phase transition accompanied by an anomaly in permittivity and a jump in conductivity by one and half orders of magnitude. In a wet atmosphere, the Li
x
Ln
5–
x
Mo
3
O
16.5–1.5
x
F
x
compounds may have proton conductivity.</description><issn>0002-7820</issn><issn>1551-2916</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNpFkE1OwzAQhS0EEqWw4QReAmrCOI5je8ECVRSQAmXRfeQ6jkhJk8pO-Nn1CEhcoGfpUXoSHEBipNG89zR6iw-hUwIh8XO5UNqEhFMe76EBYYwEkSTJPhoAQBRwEcEhOnJu4S2RIh6g10nVNbZszW79WZUvBqclfsdpjdlu_eXVQ4MpnmKShH1AQuazid-ztN5urrabVI3wkx3hx_wc62a5aro6d7h0jWttp9vOqgq_le2zf8Dsv-0YHRSqcubk7w7RbHIzG98F6fT2fnydBponccCUBKpEwr0BAYazGPICIkllnhecqSI280IkVLFI6LkGEMYQySBRUkWc0yG6-K3VtnHOmiJb2XKp7EdGIOuBZT2w7AcY_QaM-VyC</recordid><startdate>202011</startdate><enddate>202011</enddate><creator>Voronkova, Valentina</creator><creator>Kharitonova, Elena</creator><creator>Orlova, Ekaterina</creator><creator>Baldin, Egor</creator><creator>Gorshkov, Nikolay</creator><creator>Goffman, Vladimir</creator><creator>Chernyak, Sergei</creator><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-3248-3257</orcidid><orcidid>https://orcid.org/0000-0003-3754-7862</orcidid></search><sort><creationdate>202011</creationdate><title>Fluorite‐like Li x Ln 5– x Mo 3 O 16.5–1.5 x F x (Ln = La, Pr, Nd) compounds isostructural with Nd 5 Mo 3 O 16</title><author>Voronkova, Valentina ; Kharitonova, Elena ; Orlova, Ekaterina ; Baldin, Egor ; Gorshkov, Nikolay ; Goffman, Vladimir ; Chernyak, Sergei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c764-5a903a867764080e7540df02939ddf75af4ebf863a528cbc008ee19506a9a2773</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Voronkova, Valentina</creatorcontrib><creatorcontrib>Kharitonova, Elena</creatorcontrib><creatorcontrib>Orlova, Ekaterina</creatorcontrib><creatorcontrib>Baldin, Egor</creatorcontrib><creatorcontrib>Gorshkov, Nikolay</creatorcontrib><creatorcontrib>Goffman, Vladimir</creatorcontrib><creatorcontrib>Chernyak, Sergei</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of the American Ceramic Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Voronkova, Valentina</au><au>Kharitonova, Elena</au><au>Orlova, Ekaterina</au><au>Baldin, Egor</au><au>Gorshkov, Nikolay</au><au>Goffman, Vladimir</au><au>Chernyak, Sergei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fluorite‐like Li x Ln 5– x Mo 3 O 16.5–1.5 x F x (Ln = La, Pr, Nd) compounds isostructural with Nd 5 Mo 3 O 16</atitle><jtitle>Journal of the American Ceramic Society</jtitle><date>2020-11</date><risdate>2020</risdate><volume>103</volume><issue>11</issue><spage>6414</spage><epage>6423</epage><pages>6414-6423</pages><issn>0002-7820</issn><eissn>1551-2916</eissn><abstract>Li
x
Ln
5–
x
Mo
3
O
16.5–1.5
x
F
x
(0.8 ≤
x
≤ 1.4 (Ln = La), 0.4 ≤
x
≤ 1 (Ln = Pr), 0.6 ≤
x
≤ 1 (Ln = Nd)) solid solutions on the Ln
5
Mo
3
O
16
–LiLn
4
Mo
3
O
15
F joins of the Ln
2
O
3
–MoO
3
–LiF ternary systems, similar to the fluorite‐related cubic compound Nd
5
Mo
3
O
16
, have been prepared by solid‐state reactions. Substitutions of lithium on the rare‐earth site and fluorine on the oxygen site have been shown to lead to a reversible phase transition accompanied by an anomaly in permittivity and a jump in conductivity by one and half orders of magnitude. In a wet atmosphere, the Li
x
Ln
5–
x
Mo
3
O
16.5–1.5
x
F
x
compounds may have proton conductivity.</abstract><doi>10.1111/jace.17374</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0003-3248-3257</orcidid><orcidid>https://orcid.org/0000-0003-3754-7862</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0002-7820 |
| ispartof | Journal of the American Ceramic Society, 2020-11, Vol.103 (11), p.6414-6423 |
| issn | 0002-7820 1551-2916 |
| language | eng |
| recordid | cdi_crossref_primary_10_1111_jace_17374 |
| source | Wiley |
| title | Fluorite‐like Li x Ln 5– x Mo 3 O 16.5–1.5 x F x (Ln = La, Pr, Nd) compounds isostructural with Nd 5 Mo 3 O 16 |
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