Local crystal structure of multiferroic BiMnO3 studied by 57Fe probe Mössbauer spectroscopy

This paper presents a 57 Fe probe Mössbauer spectroscopy study of a BiMn 0.96 57 Fe 0.04 O 3 manganite synthesized at high pressure (6 GPa). The BiMnO 3 manganite possesses multiferroic properties and exhibits cooperative orbital ordering due to Jahn–Teller active Mn 3+ ions. 57 Fe Mössbauer spectra...

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Bibliographic Details
Published in:Inorganic materials 2016, Vol.52 (5), p.499-503
Main Authors: Glazkova, Ya. S., Belik, A. A., Sobolev, A. V., Presniakov, I. A.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Industrial Chemistry/Chemical Engineering
Inorganic Chemistry
Materials Science
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Summary:This paper presents a 57 Fe probe Mössbauer spectroscopy study of a BiMn 0.96 57 Fe 0.04 O 3 manganite synthesized at high pressure (6 GPa). The BiMnO 3 manganite possesses multiferroic properties and exhibits cooperative orbital ordering due to Jahn–Teller active Mn 3+ ions. 57 Fe Mössbauer spectra have been measured and analyzed in a wide temperature range, which includes the orbital ordering temperature of BiMnO 3 .
ISSN:0020-1685
1608-3172
DOI:10.1134/S0020168516050058