Order-disorder phase transition in CoPd thin films

• Published in: JETP letters 2008-02, Vol.86 (11), p.727-729
• Main Authors: Artem’ev, E. M., Artem’ev, M. E.
• Format: Article
• Language: English
• Subjects: Atomic; Biological and Medical Physics; Biophysics; Condensed Matter; Molecular; Optical and Plasma Physics; Particle and Nuclear Physics; Physics; Physics and Astronomy; Quantum Information Technology; Solid State Physics; Spintronics
• ISSN: 0021-3640; 1090-6487
• DOI: 10.1134/S0021364007230099

The thin films of a CoPd alloy in the equiatomic composition region are prepared by condensation at different substrate temperatures. The substrate temperature is varied from the liquid nitrogen temperature to +280°C. At low substrate temperatures, the crystal structure of the condensed films is the single-crystal blocks of the hexagonal close-packed (hcp) phase. As the substrate temperature is further increased, the domains characterized in the initial state by the microdiffraction patterns in the form of a diffuse halo appear in the films, and these domains have a clear-cut boundary with the regions indicated by point reflections in the electron diffraction patterns. At substrate temperatures from +150 to 160°C, the CoPd alloy films in the equiatomic composition region are fully amorphous. The given state is a polymorphic transformation of the martensitic type. It arises in the martensitic transformation of the low-temperature hcp phase to the high-temperature fcc phase.