Gossypol clathrates: Structure and thermal behavior of the gossypol acridine complex

The natural compound gossypol forms a stable clathrate with acridine. The composition of the clathrate is C 30 H 30 O 8 ·0.5C 13 H 9 N. The unit cell is monoclinic, C 2/ c space group, a = 11.3213(3) Å, b = 30.5957(13) Å, c = 17.0824(4) Å, γ = 94.153(2)°, V = 5901.5(3) Å 3 , M = 1153.24, Z = 8, d x...

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Bibliographic Details
Published in:Journal of structural chemistry 2011-02, Vol.52 (1), p.193-197
Main Authors: Khonkeldieva, M. T., Talipov, S. A., Izotova, L. Yu, Tilyakov, Z. G., Ibragimov, B. T., Kurtaliev, É. N.
Format: Article
Language:English
Subjects:
Atomic
Atomic/Molecular Structure and Spectra
Brief Communications
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Molecular
Optical and Plasma Physics
Physical Chemistry
Solid State Physics
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Summary:The natural compound gossypol forms a stable clathrate with acridine. The composition of the clathrate is C 30 H 30 O 8 ·0.5C 13 H 9 N. The unit cell is monoclinic, C 2/ c space group, a = 11.3213(3) Å, b = 30.5957(13) Å, c = 17.0824(4) Å, γ = 94.153(2)°, V = 5901.5(3) Å 3 , M = 1153.24, Z = 8, d x = 1.369 g/cm 3 , and R = 0.0413 for 4726 reflections. The structure of the clathrate allows one to refer this compound to the ethyl acetate isomorphic host-guest group of gossypol complexes.
ISSN:0022-4766
1573-8779
DOI:10.1134/S0022476611010264