Quantitative estimation of the discontinuous function of the solvent in aqueous electrolyte solutions

The adiabatic compression method is used to determine quantitative solvation parameters such as hydration numbers h , the molar adiabatic compressibility of hydrated complexes β h V h , the volume V 1 h and compressibility β 1 h of water in ion hydration shells, and several other properties in the t...

Full description

Saved in:
Bibliographic Details
Published in:Journal of structural chemistry 2013-02, Vol.54 (1), p.75-87
Main Author: Afanas’ev, V. N.
Format: Article
Language:English
Subjects:
Atomic
Atomic/Molecular Structure and Spectra
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Molecular
Optical and Plasma Physics
Physical Chemistry
Solid State Physics
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The adiabatic compression method is used to determine quantitative solvation parameters such as hydration numbers h , the molar adiabatic compressibility of hydrated complexes β h V h , the volume V 1 h and compressibility β 1 h of water in ion hydration shells, and several other properties in the temperature range 278.15–323.15 K. Hydration numbers are used to determine the verified activity coefficient of the solvent, γ R . The concentration dependence of the coefficient is shown to be a discontinuous function, with the discontinuity point corresponding to the complete solvation boundary.
ISSN:0022-4766
1573-8779
DOI:10.1134/S0022476613010101