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Quantitative estimation of the discontinuous function of the solvent in aqueous electrolyte solutions
The adiabatic compression method is used to determine quantitative solvation parameters such as hydration numbers h , the molar adiabatic compressibility of hydrated complexes β h V h , the volume V 1 h and compressibility β 1 h of water in ion hydration shells, and several other properties in the t...
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| Published in: | Journal of structural chemistry 2013-02, Vol.54 (1), p.75-87 |
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| Format: | Article |
| Language: | English |
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| cites | cdi_FETCH-LOGICAL-c240t-c0ce0be46668e22872fcfde57f74c899028aa477312a5a8107e49d42ff4626083 |
| container_end_page | 87 |
| container_issue | 1 |
| container_start_page | 75 |
| container_title | Journal of structural chemistry |
| container_volume | 54 |
| creator | Afanas’ev, V. N. |
| description | The adiabatic compression method is used to determine quantitative solvation parameters such as hydration numbers
h
, the molar adiabatic compressibility of hydrated complexes β
h
V
h
, the volume
V
1
h
and compressibility β
1
h
of water in ion hydration shells, and several other properties in the temperature range 278.15–323.15 K. Hydration numbers are used to determine the verified activity coefficient of the solvent, γ
R
. The concentration dependence of the coefficient is shown to be a discontinuous function, with the discontinuity point corresponding to the complete solvation boundary. |
| doi_str_mv | 10.1134/S0022476613010101 |
| format | article |
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h
, the molar adiabatic compressibility of hydrated complexes β
h
V
h
, the volume
V
1
h
and compressibility β
1
h
of water in ion hydration shells, and several other properties in the temperature range 278.15–323.15 K. Hydration numbers are used to determine the verified activity coefficient of the solvent, γ
R
. The concentration dependence of the coefficient is shown to be a discontinuous function, with the discontinuity point corresponding to the complete solvation boundary.</description><identifier>ISSN: 0022-4766</identifier><identifier>EISSN: 1573-8779</identifier><identifier>DOI: 10.1134/S0022476613010101</identifier><language>eng</language><publisher>Dordrecht: SP MAIK Nauka/Interperiodica</publisher><subject>Atomic ; Atomic/Molecular Structure and Spectra ; Chemistry ; Chemistry and Materials Science ; Inorganic Chemistry ; Molecular ; Optical and Plasma Physics ; Physical Chemistry ; Solid State Physics</subject><ispartof>Journal of structural chemistry, 2013-02, Vol.54 (1), p.75-87</ispartof><rights>Pleiades Publishing, Ltd. 2013</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c240t-c0ce0be46668e22872fcfde57f74c899028aa477312a5a8107e49d42ff4626083</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Afanas’ev, V. N.</creatorcontrib><title>Quantitative estimation of the discontinuous function of the solvent in aqueous electrolyte solutions</title><title>Journal of structural chemistry</title><addtitle>J Struct Chem</addtitle><description>The adiabatic compression method is used to determine quantitative solvation parameters such as hydration numbers
h
, the molar adiabatic compressibility of hydrated complexes β
h
V
h
, the volume
V
1
h
and compressibility β
1
h
of water in ion hydration shells, and several other properties in the temperature range 278.15–323.15 K. Hydration numbers are used to determine the verified activity coefficient of the solvent, γ
R
. The concentration dependence of the coefficient is shown to be a discontinuous function, with the discontinuity point corresponding to the complete solvation boundary.</description><subject>Atomic</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Inorganic Chemistry</subject><subject>Molecular</subject><subject>Optical and Plasma Physics</subject><subject>Physical Chemistry</subject><subject>Solid State Physics</subject><issn>0022-4766</issn><issn>1573-8779</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2013</creationdate><recordtype>article</recordtype><recordid>eNp9kN1KAzEQhYMouFYfwLu8wOokmybZSyn-FAoi6vUS04luWRPNT6Fv7671QhBkLmbgfGeYOYScM7hgrBGXjwCcCyUla4BNdUAqNldNrZVqD0k1yfWkH5OTlDYA0OpWVgQfivG5zyb3W6SYcv8-jsHT4Gh-Q7rukw0j4Esoibri7W81hWGLPtPeU_NZcEJwQJtjGHb5Wy4Tnk7JkTNDwrOfPiPPN9dPi7t6dX-7XFytassF5NqCRXhBIaXUyLlW3Fm3xrlySljdtsC1MUKphnEzN5qBQtGuBXdOSC5BNzPC9nttDClFdN1HHB-Ku45BN-XU_clp9PC9J42sf8XYbUKJfjzzH9MXPd9sLA</recordid><startdate>20130201</startdate><enddate>20130201</enddate><creator>Afanas’ev, V. N.</creator><general>SP MAIK Nauka/Interperiodica</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20130201</creationdate><title>Quantitative estimation of the discontinuous function of the solvent in aqueous electrolyte solutions</title><author>Afanas’ev, V. N.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c240t-c0ce0be46668e22872fcfde57f74c899028aa477312a5a8107e49d42ff4626083</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2013</creationdate><topic>Atomic</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Inorganic Chemistry</topic><topic>Molecular</topic><topic>Optical and Plasma Physics</topic><topic>Physical Chemistry</topic><topic>Solid State Physics</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Afanas’ev, V. N.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Afanas’ev, V. N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Quantitative estimation of the discontinuous function of the solvent in aqueous electrolyte solutions</atitle><jtitle>Journal of structural chemistry</jtitle><stitle>J Struct Chem</stitle><date>2013-02-01</date><risdate>2013</risdate><volume>54</volume><issue>1</issue><spage>75</spage><epage>87</epage><pages>75-87</pages><issn>0022-4766</issn><eissn>1573-8779</eissn><abstract>The adiabatic compression method is used to determine quantitative solvation parameters such as hydration numbers
h
, the molar adiabatic compressibility of hydrated complexes β
h
V
h
, the volume
V
1
h
and compressibility β
1
h
of water in ion hydration shells, and several other properties in the temperature range 278.15–323.15 K. Hydration numbers are used to determine the verified activity coefficient of the solvent, γ
R
. The concentration dependence of the coefficient is shown to be a discontinuous function, with the discontinuity point corresponding to the complete solvation boundary.</abstract><cop>Dordrecht</cop><pub>SP MAIK Nauka/Interperiodica</pub><doi>10.1134/S0022476613010101</doi><tpages>13</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-4766 |
| ispartof | Journal of structural chemistry, 2013-02, Vol.54 (1), p.75-87 |
| issn | 0022-4766 1573-8779 |
| language | eng |
| recordid | cdi_crossref_primary_10_1134_S0022476613010101 |
| source | Springer Link |
| subjects | Atomic Atomic/Molecular Structure and Spectra Chemistry Chemistry and Materials Science Inorganic Chemistry Molecular Optical and Plasma Physics Physical Chemistry Solid State Physics |
| title | Quantitative estimation of the discontinuous function of the solvent in aqueous electrolyte solutions |
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