In situ synthesis and structure of FeCl4(4,4′-diethyl-4,4′-bipyh) (bipy = bipyridine)

A novel viologen(4,4′-bipyridinium)-based compound FeCl 4 (4,4′-diethyl-4,4′-bipyH) ( 1 ) (bipy = bipyridine), in which 4,4′-diethyl-4,4′-bipyH ( MQ + ) was generated in situ , is synthesized via the hydrothermal reaction and structurally characterized by single crystal X-ray diffraction. The crysta...

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Bibliographic Details
Published in:Journal of structural chemistry 2013-02, Vol.54 (1), p.173-176
Main Authors: Chen, W. -T., Luo, Z. -G., Liu, D. -S., Xu, Y. -P., Luo, Q. -Y.
Format: Article
Language:English
Subjects:
Atomic
Atomic/Molecular Structure and Spectra
Brief Communications
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Molecular
Optical and Plasma Physics
Physical Chemistry
Solid State Physics
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Summary:A novel viologen(4,4′-bipyridinium)-based compound FeCl 4 (4,4′-diethyl-4,4′-bipyH) ( 1 ) (bipy = bipyridine), in which 4,4′-diethyl-4,4′-bipyH ( MQ + ) was generated in situ , is synthesized via the hydrothermal reaction and structurally characterized by single crystal X-ray diffraction. The crystal structure analysis reveals that the title compound features an isolated structure based on 4,4′-diethyl-4,4′-bipyH moieties and an iron atom terminally bound by four chlorine atoms. The 4,4′-diethyl-4,4′-bipyH moieties and (FeCl 4 ) − anions are interconnected by hydrogen bonds to form a 3D supramolecular framework.
ISSN:0022-4766
1573-8779
DOI:10.1134/S0022476613010265