Crystal structure of the copper(I) complex Cu(py-Clan)(PPh3)I

A mixed ligand copper(I) Schiff base complex [Cu(py-Clan)(PPh 3 )I], where py-Clan = = 4-chlorophenylpyridine-2-ylmethyleneamine, is synthesized and structurally characterized by single crystal X-ray crystallography. In this complex, the copper(I) ion is in a distorted four-coordinate tetrahedral ge...

Full description

Saved in:
Bibliographic Details
Published in:Journal of structural chemistry 2015, Vol.56 (1), p.175-178
Main Authors: Khalaji, A. D., Jafari, K., Fejfarova, K., Dusek, M.
Format: Article
Language:English
Subjects:
Atomic
Atomic/Molecular Structure and Spectra
Brief Communications
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Molecular
Optical and Plasma Physics
Physical Chemistry
Solid State Physics
Citations: Items that this one cites
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A mixed ligand copper(I) Schiff base complex [Cu(py-Clan)(PPh 3 )I], where py-Clan = = 4-chlorophenylpyridine-2-ylmethyleneamine, is synthesized and structurally characterized by single crystal X-ray crystallography. In this complex, the copper(I) ion is in a distorted four-coordinate tetrahedral geometry. The Schiff base py-Clan ligand acts as a chelating ligand and coordinates to the copper center via two nitrogen atoms. The [Cu(py-Clan)(PPh 3 )I] complex crystallizes in the monoclinic space group P 2 1 / c with unit cell parameters: a = 10.3339(12) Å, b = 34.524 Å, c = 8.3940 Å, β = 114.759(8)°, V = 2719.4(5) Å 3 and Z = 4.
ISSN:0022-4766
1573-8779
DOI:10.1134/S0022476615010230