Interaction between Pt(IV) and Pd(II) chloro complexes in solution and on the γ-Al2O3 surface

The conversions of a mixture of platinum(IV) and palladium(II) chloro complexes in aqueous solution and on the γ-Al 2 O 3 surface at 25–150°C are reported. Heat treatment can initiate interaction between the complexes, both dissolved and adsorbed. The hydrolysis of the chloroplatinate ion is acceler...

Full description

Saved in:
Bibliographic Details
Published in:Kinetics and catalysis 2010-02, Vol.51 (1), p.105-112
Main Authors: Bel’skaya, O. B., Gulyaeva, T. I., Arbuzov, A. B., Duplyakin, V. K., Likholobov, V. A.
Format: Article
Language:English
Subjects:
Catalysis
Chemistry
Chemistry and Materials Science
Physical Chemistry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The conversions of a mixture of platinum(IV) and palladium(II) chloro complexes in aqueous solution and on the γ-Al 2 O 3 surface at 25–150°C are reported. Heat treatment can initiate interaction between the complexes, both dissolved and adsorbed. The hydrolysis of the chloroplatinate ion is accelerated by the palladium chloro complex, whose composition remains unchanged.
ISSN:0023-1584
1608-3210
DOI:10.1134/S0023158410010179