Synthesis and physicochemical properties of new hafnium fluoro complexes (NH4)6MHf4F23 (M = K, Rb, Cs)

Ammonium-containing hafnium fluoro complexes (NH 4 ) 6 MHf 4 F 23 (M = K, Rb, Cs), which crystallize in orthorhombic symmetry, were synthesized and studied. Their unit cell parameters were determined. The IR absorption spectra of the synthesized complexes were studied in the region of 350–4000 cm −1...

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Bibliographic Details
Published in:Russian journal of inorganic chemistry 2012, Vol.57 (12), p.1535-1539
Main Authors: Antokhina, T. F., Kaidalova, T. A., Savchenko, N. N., Ignat’eva, L. N.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Synthesis and Properties of Inorganic Compounds
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Summary:Ammonium-containing hafnium fluoro complexes (NH 4 ) 6 MHf 4 F 23 (M = K, Rb, Cs), which crystallize in orthorhombic symmetry, were synthesized and studied. Their unit cell parameters were determined. The IR absorption spectra of the synthesized complexes were studied in the region of 350–4000 cm −1 .
ISSN:0036-0236
1531-8613
DOI:10.1134/S0036023612120029